电气石与铜锌合金在水中的协同机制研究.docVIP

河 北 工 业 大 学 毕 业 论 文 作 者： 王辉 学 号： 111967 学 院： 材料科学与工程学院 系(专业)： 功能材料 题 目：电气石与铜锌合金在水中的协同机制研究 指导者： 孟军平 副研究员 评阅者： 2015年 6月 12日 毕业设计（论文）中文摘要 电气石与铜锌合金在水中协同机制研究 摘要： 本课题将铜锌合金和电气石与水作用，系统研究铜锌合金和电气石对水的pH、表面张力、电极电位、电导率等指标的变化规律；采用锅炉模拟装置，研究经铜锌合金和电气石处理的水结垢特点；利用SEM、XRD等手段研究铜锌合金与电气石对水垢形成的微观影响机制。 关键词：铜锌合金 电气石 水垢 碳酸钙 晶体结构 毕业设计（论文）外文摘要 Title Study on the synergistic reaction of tourmaline and copper zinc alloy in Water Abstract In this paper, the water was treated by copper-zinc alloy and tourmaline ball. The change of water parameters contain pH values, surface tension, electrode potential and conductivity was studied. The scaling characteristics of the water treated by the copper-zinc alloy and tourmaline were researched by the mine-made boiler simulator. The microscopic influence mechanism of scale formation was explored by SEM,XRD and etc. The results showed that the pH values of water rose from 7.419 to 7.630, the surface tension was reduced to 52.99 mN / m from 58.91 mN / m and the electrode potential was dropped from -15.55 mV to -26.55 mV after treated by 10 g copper-zinc alloy in 800 mL solution of 500 mg/L [Ca2+][HCO3-]. Copper-zinc alloy can make Zn2+ of dissolution to change the direction of crystal growth by forming the tiny primary battery reaction. The polarity of the tourmaline can electrolysis of water molecules and reduce the association degree of water molecules. When both synergies, tourmaline stimulate water activity, strengthen Zn ions stripping effect, and strengthen copper-zinc alloy galvanic cell reaction. The fouling crystal was converted to aragonite calcium carbonate easily after treated by the copper-zinc alloy and tourmaline ball. Key words：copper-zinc alloy tourmaline scale calcium carbonate crystal structure 目录 1 绪论..............................................................1 1.1研究目的与意义1 1.2国内外研究现状1 1.2.1常见水垢及性质1 1.2