热解温度对褐煤半焦成浆特性影响的实验研究.pdf

第33 卷 第8 期 中 国 电 机 工 程 学 报 Vol.33 No.8 Mar.15, 2013 36 2013 年3 月15 日 Proceedings of the CSEE ©2013 Chin.Soc.for Elec.Eng. 0258-8013 (2013) 08-0036-08 TQ 536 A 470 20 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 热解温度对褐煤半焦成浆特性影响的实验研究 刘明强，刘建忠，王睿坤，周俊虎，岑可法 (能源清洁利用国家重点实验室(浙江大学) ，浙江省 杭州市 310027) Effects of Pyrolysis Temperature on Slurry Ability of Lignite Semi-coke LIU Mingqiang, LIU Jianzhong, WANG Ruikun, ZHOU Junhu, CEN Kefa (State Key Laboratory of Clean Energy Utilization(Zhejiang University), Hangzhou 310027, Zhejiang Province, China) ABSTRACT: The low temperature (450-650 ℃ ) pyrolysis 温热解能有效脱除褐煤中的水分，促进含氧基团的分解，提 method was used to modify lignite. The effect of pyrolysis 高煤阶。热解后，煤的孔隙结构发生变化，热解终温升高， temperature on the slurry ability of lignite semi-coke was 孔比表面积和孔容积减小。 studied. The coal characteristics and microscopic pore structure 关键词：低温热解；褐煤；半焦；水煤浆；成浆特性 characteristics were investigated to explain the change of the slurry ability. Herschel-Bulkley model was chosen to carry out 0 引言 fitting analysis of slurry rheological characteristics， which 褐煤，是煤化程度最低的矿产煤，是一种介于 directly indicates how slurry rheological characteristics 泥炭与沥青煤之间的棕黑色、无光泽的低阶煤。褐 changes as the concentration slurry alters. The results show that 煤的水分和挥发分含量很高，易自燃，不利于长途 low temperature pyrolysis effectively improves the slurry ability of lignite. The maximum solid concentration increases 运输和储存[1] 。随着能源需求的增加和煤炭资源的大 maximally from 44.31% to 66.78%. Increasing temperature 量消耗，无烟煤、烟煤等高阶煤消耗量日益增加，