氧化石墨烯吸附增强应用的展望 - arXivorg.PDF

氧化石墨烯吸附增强应用的展望 孙 凌 1,2 1. 北京古月新材料研究院，北京工业大学 2. 新材料与产业技术北京研究院 Email: sunling@bjut.edu.cn 摘要： 使用吸附剂是水体修复重要手段，碳是一类重要的吸附剂材料。不同形态的碳材料展现出不同的污染吸附 去除能力。氧化石墨烯作为二维碳材料石墨烯衍生的氧化物，继承后者的二维形貌，但结构上嫁接有丰富且差异分 布的多种含氧基团。在水中自由舒展的氧化石墨烯类于平面超级大分子，布朗运动作用下会大量接触吸附质，发生 强大吸附作用；但含氧基团吸附机制差异、分布差异造成石墨烯表面吸附物质分布相对不均匀。因此，调控表面含 氧基团及其分布是吸附增强的重要手段，由此演绎出来的原位基团调控致吸附增强方法是十分有潜力的。 Graphene oxide adsorptive power from better to more via an enhanced route in perspective 1,2 Sun，Ling 1. Beijing Guyue New Materials Research Institute, Beijing University of Technology, Beijing 2. Materials and Industrial Technology Research Institute, Beijing Abstract: Adsorption is one important way applied to water decontamination, where carbon is commonly used as highly effective absorbent. Carbon of different morphologies and structures normally demonstrate distinct capabilities to adsorption-typed decontaminations. Graphene oxide is regarded as the oxidative derivative of graphene, maintaining its 2D morphology-featuring structure while location-dependently immobilized with a large amount of various oxygen-involving functional moieties on both sides. Free-standing graphene oxide tends to fully unfold in water and behave in macromolecular-like Brownian motion. Therefore, high-performance adsorption occurs during the process of interacting with large amount of sorbates, during which an unevenness of effective adsorptive site distribution turns out for targeted matter due to functional group-to-sorbate interaction mechanism differentiation as well as groups’ inherent location specifications. Thus, oriented manipulation of surficial functional moieties and their site distribution is potentially a way to further enhance the adsorptive performances, and this could go even better if considering combining adsorption and an in-situ manipulation at the same time. 全球范围内，尤其是发展中、不发达国家，水与土壤等环境污染问题比较突出，环境修复需求迫 切。氧化石墨烯是环境修复材料领域中的研究热点，是极具发展潜力的碳吸附材料。以氧化石墨烯为 吸附材料的研究论文数量（WO