低QI浸渍剂沥青渗透性能研究.pdfVIP

万方数据 摘 要 选择两类具有相近流变性能的黏结剂沥青和浸渍剂沥青，模拟炭材料的微孔分布 选择滤材测定了两类沥青的渗透率，对比研究了浸渍剂沥青和黏结剂沥青的渗透性能 差异，结果表明，浸渍剂沥青的渗透性能远优于黏结剂沥青，浸渍剂沥青的渗透率为 黏结剂沥青相应值的3.54～22.13 倍，两类煤沥青的渗透性差异是由于其QI 含量不同 造成的，浸渍剂沥青极低的QI 含量(0.2% 以下)大大降低了煤沥青向多孔滤材内孔隙的 渗透阻力，从而为提高沥青的浸渍效果创造了有利条件。 微细炭黑粉的添加使浸渍剂沥青的渗透性能明显变差，沥青浸透率降低幅度高达 39%～84%。与原生QI 结构性质相类似的炭黑粉能较好地模拟浸渍剂沥青中原生QI 颗粒对沥青渗透性能的影响,进一步证实了沥青中原生QI 组分对浸渍剂沥青渗透性能 的负面影响。向浸渍剂沥青中添加少量表面活性剂油酸可明显改善浸渍剂沥青的渗透 性能，油酸改性沥青渗透率提高幅度为 15%～55%。低QI 浸渍剂沥青性能指标与组 分组成之间存在着较好的相关性。 关键词：浸渍剂沥青；原生QI；渗透性；炭黑；油酸 I 万方数据 Abstract The impregnant pitch and binder pitch with the similar rheological properties were selected. The permeabilities of two kinds of coal-tar pitch were determined by simulating micropore sizes of carbon materials. The permeability differences between both pitches were investigated. The results show that the permeability of impregnant pitch is superior to the binder pitch. The permeability of impregnant pitch is between 3.54 to 22.13 times that of binder pitch. These differences result from the different QI contents in two kinds of pitch. The impregnant pitch contains very low QI content (less than 0.2%), which greatly reduces the permeability resistance of coal-tar pitch to the porous filter. This has created favorable conditions for enhancing the efficiency of impregnation. The addition of carbon black into the impregnant pitch has reduced the permeability of pitch by 39% ～84%.It is shown that the primary QI has negative impact on the permeability of pitch by simulating primary QI with carbon black. Modification of the impregnant pitch by