饮用水中内分泌干扰物甲草胺的O3 氧化降解机制研究.PDF

DOI :10.13227/j.hjkx.2004.02.009 25 2 　　　　　　 Vol.25, No.2 2004 3 Mar., 2004 ENVIRONMENTA L SCIENCE O 3 1 1 ＊ 2 , , (1., 　100085;2., 　 100044) :.、、UV ., O , 3 30 min 94%, TOC 35%, O CO 3 2 H O.UV , , 2 pH 5.96 3.94, . :;O ;; 3 :R123.6;X328　:A 　:0250-3301(2004)02-0043-04 Degradation Mechanism of Ozonation of Endocrine Disruptor (Alachlor )in Drinkingwater 1 1 2 LI Hai-yan , QU Jiu-hui , HAO Xiang (1.State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 　100085, China;2.Civil and Construction Engineering College, Northern Jiaotong University, Beijing 　 100044, China) Abstract:In this study, the degradation mechanism of an endocrine disruptor, alachlor, by ozonation was investigated.HPLC, GC, IC and UV were used to follow the intermediate and ultimate oxidation products produced in the ozonation of alachlor.The results show ed that 94%alachlor was degraded after being directly ozonated for 30 min at acidic condition.But alachlor could not be com- pletely degraded to CO and H O, w hich was 35 percentage of TOC removal after being ozonated for 180min.Several intermediate 2 2 oxidation products w ere observed by UV and HPLC.Organic acidsof small molecular were produced in the ozonation, resulting in the decreasing of pH from 5.96 to 3.94.The broken of alachlor structure w asverified by the creation of inorganic ions in the ozonation. Key words:alachlor;ozonation;endocrine disruptor;degradation mec