硫化锌氧压浸出过程的φpH.pdf

20 8 2010 8 Vol.20 No.8 The Chinese Journal of Nonferrous Metals Aug. 2010 1004-0609(2010)08-1636-09 φpH 1, 2 1, 2 1, 2 1, 2 1, 2 (1. 110819 2. 110819) Θ Θ Θ ZnS-H O G φ pH 2 φpH φpH S Zn2+pH ZnS (ICP)XRD XRF 15%1.1 MPa160 8:1 90 min480 r/min 98.86%81.33%φ pH ZnS-H O φpH 2 TF803.21 A φpH figure during oxidative pressure leaching of zinc sulfide MU Wang-zhong1, 2, ZHANG Ting-an1, 2, LÜ Guo-zhi1, 2, GU Yan1, 2, DOU Zhi-he1, 2 (1. School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China; 2. Key Laboratory of Ecological Utilization of Multi-metal Intergrown Ores, Ministry of Education, Northeastern University, Shenyang 110819, China) Θ Θ Θ Abstract: The values of G , φ or pH and relevant potential expressions were obtained through thermodynamical calculation, and φpH figures of ZnS-H2O system at different ionic activities and different oxygen partial pressures were obtained. With increasing the ionic activity, the stable regions of S and Zn2+ in the φpH figures become gradually large, but the limit of pH in the stable region becomes gradually small. With increasing the oxygen partial pressure, the stable region of H2O become large. The oxidative pressure leaching experiments of ZnS were done in autoclave, the leaching solution and