全自动石墨消解-电感耦合等离子体质谱测定鱼、 虾等生物样品中铜、镉.PDF

8 1 Vol. 8No. 1 2017 1 Journal of Food Safety and Quality Jan. , 2017 - 4 * 郑红艳 , 郭雪勤, 朱志勋, 翟婉盈 (, 430010) 摘要: 目的 方法 10.0 µg/L Rh , --, , - (inductively coupled plasma mass spectrometry,ICP-MS)4 结果 0.001~0.200 μg/L , 0~2.30%, 91.4%~113.4%(GSB-28)结论 , , , 关键词:; ; ; ; Determination of Cu, Cd, Cr and Zn in fish and shrimp by automated graphite digestion combined with inductively coupled plasma mass spectrometry * ZHENG Hong-Yan , GUO Xue-Qin, ZHU Zhi-Xun, ZHAI Wan-Ying (Water Environment Monitoring Center of Yangtze River Basin, Wuhan 430010, China) ABSTRACT: Objective To develop an easy, fast, and accurate method for the simultaneous determination of Cu, Cd, Cr and Zn in biological samples like fish and shrimp. Methods Using 10.0 µg/L Rh as internal standard element, nitric acid, hydrogen dioxide and perchloric acid as digestion acids,fish, shrimp and other biological samples were digested by automatic graphite digestion instrument, and the method for the simultaneous determination of 4 metal elements of copper, cadmium, zinc and chromium by graphite digestioncombined with inductively coupled