分光光度法测定NdFeB镀液中钕的含量.pdfVIP

2014 年 11 月 电镀与精饰 第 36 卷第 11 期(总2ω 期) • 33 • doi: 10. 3969/j. issn. 1∞1-3849.2014.1 1.侃 分光光度法测定 NdFeB 镀液中敏的含量 马艳1 ，王萃2 ，玄翠娟3 ，张岩3 ，杨仲年3 (1.山东中医药大学药学院，山东济南 250355;2. 山东师范大学化学化工与材料科学学院，山东 济南 25∞14;3. 滨州学院化学工程系，山东滨州 256603) 摘要:采用直接分光光度法，选用 740nm 波长，测定了 NdFeB 镀液中仕的含量，加入盐酸是膳消除 Fe( m) 的干扰。结果表明，Nd(m)质量浓度在0.1-6.0 g/L 范围内时，吸光度和质量浓度具有良 好的线性关系，线性相关系数大于0.9999 ，检测下限为 0.02 g/L。用于实际样品分析，加标回收率 为 97.8% -1∞.8% ，测定结果的相对标准偏差为 0.4% -0.5% 。此方法精密度和准确度好，简单 快速高效。 关键词:分光光度法:仕的含量;测定;NdFeB 镀液 中固分类号:TQI53.2 文献标识码:A Spectrophotometric Determination of Nd( 皿) Content in NdFeß Electroplating Solution MA Yan 1 , WANG Cui2 , XUAN Cui-juan3 , ZHANG Yan3 , YANG Zhong-nian3 ( 1. College of Phannacy , Shandong University of Traditional Chinese Medicine ,Jinan 250355 , China; 2. College of Chemistry , Chemical Engineering and Materials Scienc , Shandong Normal University , Jinan 25∞14 ,China; 3. Department of Chemical Engineeri吨，Binzhou University ,Binzhou 256603 ,China) Abs位act: A method w.描 developed to determine Nd( m) content in NdFeB electroplating solution by u- sing direct spectrophotometry , selecting an optimal wavelength of 740 nm , and adding hydroxylamine hydrochloride to eliminate the interference of Fe( m) ion. Results showed 由at when Nd( m) m嗣s con- centration w嗣 within the range of O. 1 - 6.0 g/L ,the absorbance and concentration had a good linear rela- tionship ,the correlation coefficient w嗣 greater 也an O. 9999 and the detection limit w描 0.02 g/L. For real samples analyzing ,the recove可 rate of standard addition w臼 97.8% -1∞.8% ,and the relative stand- ard deviations w描 0.4% -0.5%. So，也is method w副 suitable for on-line determination due to its high accuracy ,easy operation and high e