分光光度法测定乳及乳粉中的硫氰酸钠.pdfVIP

@ 中国乳品工业 zgrpgy@163.com f{q!rYINDUSTRY 分光光度法测定乳及乳粉中的硫氨酸铺 张丽宏，黄晓栋，哪来明，懵像阻，梁杰 (东北农业大学国家乳制品质量监督检测中心，哈尔滨 150028) 摘 要:研究了使用分光光度法测定乳及乳粉中的硫氨酸纳及手L及乳粉中硫氨酸钩的测定条件，获得了较好的结果。本方法的回 收率在92.0% - 99.5%之间，标准曲线的回归方程的相关系数卢0.9998， RSD::;4.51%。乳最低检出F且为。.05 mg/L ;草L粉最低检出Flt 0.5 mg/kg 本文研究的测定方法操作简便、测定成本较低、准确度高，可用于乳及乳粉中硫氯酸纳的定量测定。 o 关键词:硫氯殴纳;辛L; 手L粉;分光尤度法;测定 中固分类号:TS252.7 文献标识码:A 文章编号:1001-2230(2016)07-0041-03 Determination of sodium thiocyanate in milk and milk powder by spectropho- tometric method ZHANG Li-hong , HUANG Xia。一lin ， E Lai-ming , FU Xu-yang , LIANG Jie (The Natíonal Dairy Testing Center, Northeast Agricultural University ,Harbin 150028 ,China) Abstract: This paper studies the use of dete口nination of milk and milk powder in sodium thiocyanate spectrophotometric method. Study on the detennination of the conditions of sodium thiocyanate in milk and milk powder , good results are obtained. The recoveries of this method in 92% - 99 .5%, r=0.9998 ∞rrelation coefficient of regression equation of standard curve , RSD is less than or equal to 4 .5 1% (n=8). The low- est detection limit of 0.05 mg/L m监; milk powder detection limit ofO.5 mg/kg. Method for the dete口由nation of the deterrnination of sim- ple operation , low cost, high accuracy , can be used for the deterrnination of sodium thiocyanate in milk and milk powder. Key words: sodium thiocyanate; milk; milk powder; spectrophotometry; dete口runatJon. 化，得到了较好的测定方法。 言主F 。引 E司 1 实验 纯硫氨酸铀是白色结晶固体，易溶于水、乙醇、丙 1.1 仪器与设备 与酸和强氧化剂反应，熔点约为 酣.比重1.735 0 287 c。硫氨酸铀是有毒有害品，少量的食入就会对 可见紫外分光光度计(VIS-7200A 型) ，电子天平 人体造成极大伤害。硫氨酸铀的毒性主要由其在体