分析微波和等离子体辅助次氯酸钠浸出含砷铜矿脱砷工艺概要.doc

微波和等离子体辅助次氯酸钠浸出含砷铜矿脱砷工艺 赵卓英,b，齐越,b，杜冬云,b (中南民族大学环境科学与工程研究所，化学与材料科学学院催化材料科学国家民委教育部共建重点实验室，武汉 430074） 摘要：采用次氯酸钠浸出方法降低含砷铜矿中的砷含量。最佳工艺条件为：温度30 ℃粒度5474 μm、NaClO浓度0.39 mol/LNaOH用量矿样时间90 min液固比401（mL/g）砷浸出率47.53%。微波场和辉光放电等离子体场辅助次氯酸钠浸出，砷浸出率分别为%、72.88%，处理后铜矿中砷含量分别降至0.1%、0.12%，均满足铜精矿二级品砷含量的指标要求。 关键：次氯酸钠含砷铜矿微波辉光发电等离子体TF802+.63 文献标志码：A 文章编号：1007-7545（2015）07-0000-00 Arsenic Removal from Arsenic-bearing Copper Ore by Sodium Hypochlorite Leaching Assisted with Microwave and Low-pressure Glow Discharge Plasma ZHAO Zhuo-yinga,b，QI Yue,b，DU Dong-yun,b (a. Institute of Environment Engineering and Science, b. Key Laboratory of Catalysis and Materials Science of State Ethnic Affairs Commission, Ministry of Education, School of Chemistry and Materials Science, South Central University for Nationalities, Wuhan 430074, China) Abstract: Arsenic content was reduced by leaching arsenic-bearing copper ore with sodium hypochlorite under alkaline oxidizing condition. The results show that arsenic leaching rate is 47.53% under the optimum conditions including temperature of 30 ℃, particle size of 54~74 μm, sodium hypochlorite concentration of 0.39 mol/L, sodium hydroxide dosage of 1.67% of sample ore, leaching time of 90 min, and ratio of liquid to solid of 40︰1(mL/g). rsenic leaching rates of sodium hypochlorite leaching under microwave and low-pressure glow discharge plasmas are 66% and 72.88% respectively, while arsenic content in treated copper ore is reduced to 0.15% and 0.12% respectively, which meets arsenic index requirement of second grade copper concentrates. Key words: sodium hypochlorite; arsenic-bearing copper ore; arsenic removal; microwave; low-pressure glow discharge plasmas 随着铜精矿资源日益枯竭杂质含量高的复杂矿日渐增多，铜精矿中的砷影响产品质量，还会给工序一系列问题[1]。我国铜精矿质量标准（YS 318-2007）规定冶炼精矿中砷的含量应小于0.3%，而铜精矿二级品含量的指标要求为小于0.2%。为了尽可能地提高精矿品位，在冶炼前，必须通过预处理尽可能减少其中杂矿含量以保证冶炼过程的顺利进行，从而减少冶炼过程原辅材料的消耗，也有利于杂质元素对冶炼过程的干扰。 目前，铜矿预处理除砷一是在选矿时浮选除砷二是采用湿法工艺如焙烧[]、碱浸[]、酸浸[]、加压氧化浸出[1-12]、细菌浸出[115]等对含砷铜精矿预处理除砷。其中，浮选除砷不适用于铜砷伴生矿物，在常规浮选过程中含砷铜矿会不