杭州市大气PM2.5消光特性研究详解.docVIP

杭州市大气PM2.5 卢慧剑1,2 金 均1 王琼真1 何 奕2 晁 娜1 吴 建1# （1.浙江省环境保护科学设计研究院，浙江 杭州 310007；2.浙江大学化学工程与生物工程学院，工业生态与环境研究所，浙江 杭州 310027） 第一作者：卢慧剑，男，1989年生，硕士研究生，主要从事大气污染防控研究。#通讯作者。 *环保公益性行业科研专项（No.201409008）；浙江省重大科技专项重点社会发展项目（No.2014C03025）；浙江省环保科研计划项目（No.2014A001、No.2014A007）；浙江省培育创新载体项目（No.2014F10042）。 摘要2013年10月10日11月2日，杭州市进行了采样，并定量分析了化学成分通过消光系数和能见度的计算确定了杭州市能见度与消光系数的关系。结果，PM2.5日平均浓度133.1 μg/m3，平均值为80.5 μg/m3，消光系数为15.9~657.7 Mm-1，为37 Mm-1，消光系数的贡献因子为(NH4)2SO4NH4NO3、颗粒有机物（POM）和元素碳（EC）。二次粒子是影响杭州市大气能见度的最主要因素。Koschmieder公式能见度与消光系数Koschmieder系数为， 关键词PM2.5 能见度 消光系数 Study on the characteristics of light extinction coefficients of atmospheric PM2.5 in Hangzhou,China LU Huijian1,2,JIN Jun1,WANG Qiongzhen1,HE Yi2,CHAO Na1,WU Jian1.（1.Environmental Science Research Design Institute of Zhejiang Province,Hangzhou Zhejiang 310007;2.Industrial Ecology and Environment Research Institute,College of Chemical and Biological Engineering,Zhejiang University,Hangzhou Zhejiang 310027） Abstract: In order to explore the causes of visibility in Hangzhou,PM2.5 samples were collected and PM2.5 compositions were analyzed from October 10th to November 2nd,2013.The relationship between light extinction coefficeints and visibility was established.Results showed that daily PM2.5 mass concentrations were 26.0-133.1 μg/m3 with a mean value of 80.5 μg/m3.The light extinction coefficients were 145.9-657.7 Mm-1 with a mean value of 372.2 Mm-1.The main contributors for light extinction coefficients were ammonia sulfate,ammonium nitrate, particulate organic matter (POM) and elements carbon (OC).Therefore, secondary particles were the main factors to affect the atmospheric visibility in Hangzhou.Koschmieder formula was applied to describe the relationship between the visibility and the light extinction coefficient.The estimated Koschmieder coefficient (1.81) could predict the visibility in Hangzhou. Keywords: atmosphere；PM2.5；visibility；light extinction coefficients 大气雾霾和PM2.5污染最直接的后果就是能见度下降随着生活环境的要求不断，大气能见度下降已经成