常用有机溶剂的纯化(外国英语资料).docVIP

常用有机溶剂的纯化 carbon tetrachloride Boiling point 76.8 DEG C, refractive index 1.4603, relative density 1.595. Carbon disulfide in carbon tetrachloride reached 4%. Purification, 1000mL solution of carbon tetrachloride and 60g potassium hydroxide dissolved in 60mL water and 100mL ethanol mixed together at 50~60 DEG C to shake the 30min, then washed with water, then the carbon tetrachloride by the method of repeated operation again (half the amount of external hydrogen). Residual ethanol in carbon tetrachloride can be removed with calcium chloride. Finally, carbon tetrachloride was dried with calciu