mg2 ni 纳米贮氢合金的电化学性能研究.pdf

CNIC-01943 CAEP-0217 Mg Ni 纳米贮氢合金的电化学性能研究 2 张玲周晓松彭述明 (中国工程物理研究院核物理与化学研究所，绵阳，621900) 摘要 采用机械合金化方法制备了 MgzNi 纳米材料。不同扫描速度/ 温度下的循环伏安测试结果表明:样品的氧化峰电位随扫描速度的 加快而正移;室温下的吸氢性能显著增强，吸放氢速度随温度的升高 而加快oX 射线小角散射结果表明:该材料具有 1-5 nm 以及 5- 10 nm的粒度分布，较小的粒度使得吸放氢反应的活性位置增多和放 氢的扩散路径减少，这可能是导致材料贮氢性能显著提高的原因o 循环寿命的快速检测结果表明:MgzNi 纳米贮氢合金电极的活性很 好;经过 200 次循环后，其容量保持率为 66% 0 在电极一侧涂覆环氧 树脂后其电化学活性未受到明显影响，容量保持率优于未涂覆的电 极;但阴极峰和阳极峰电流值显著下降，说明吸放氢反应的速率以及 充放电程度有所降低o 关键词 Mg Ni 机械合金化 循环伏安法 X 射线小角散射 2 129 The Electrochemical Characteristics of Mg Ni 2 Nanocrystalline Hydrogen Storage Alloy (In Chinese) ZHANG Ling ZHOU Xiaosong PENG Shuming Clnstitute of Nuclear Physics and Chemistry , CAEP , Mianyang , 621900) ABSTRACT The nanocrystalline Mg2 Ni materials were prepared by mechanical allo- ying. The cyclic voltammetry results indicated that the potential of oxidation peak was shift as the scan rate increased and the absorption property of Mg Ni 2 prepared by mechanical alloying was increased even at ambient temperature. The absorption and desorption of hydrogen in Mg2 Ni alloy were remarkably accelerated with the rising temperature. Small angel X-ray scattering results indicated that the Mg Ni powder have 15 nm and 510 nm particle size dis-