中文模版2012-06 - 硅酸盐学报.doc

铽掺杂对SrAl2O4:Eu2+,Dy3+发光性能的影响 樊国栋，肖国平，张 昭，李刚辉 (陕西科技大学化学与化工学院，教育部轻化工助剂化学与技术重点实验室，西安 710021) 摘 要：以尿素为燃料，采用快速燃烧法在650 ℃合成了Tb3+掺杂的SrAl2O4:Eu2+,Dy3+新型长余辉光致发光材料。研究了Tb3+掺杂对Eu2+,Dy3+共激活的铝酸盐长余辉发光材料的发光特性的影响。X射线衍射分析结果表明：当Tb3+的掺杂量x = 0.17%时，合成的样品结构为单相SrAl2O4单斜晶系。光致发光测试结果表明：样品的激发光谱为峰值位于345 nm附近的连续宽带谱，发射光谱为峰值位于510 nm左右的连续宽带谱。余辉衰减曲线结果显示，Tb3+的适量掺杂可以提高铝酸锶的余辉性能。与SrAl2O4:Eu2+,Dy3+相比，掺杂Tb3+有利于形成结晶度良好的固溶体，样品中的晶体细密紧凑，颗粒粒径约为100 nm。 关键词：燃烧法；长余辉磷光材料；铕；镝–5648(2012)01– 网络出版时间： DOI： 网络出版地址： Modification of Optical Properties of SrAl2O4:Eu2+,Dy3+ Phosphor by Terbium Doping FAN Guodong，XIAO Guoping，ZHANG Zhao，LI Ganghui (Key Laboratory of Auxiliary Chemistry Technology for Chemical Industry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi University of Science Technology, Xi′an 710021, Shaanxi, China) Abstract: The SrAl2O4:Eu2+,Dy3+ long persistence phosphor doped with Tb3+ was synthesized by the combustion method at the temperature of 600 ℃ using urea as a fuel. The modification of optical properties of the phosphor was studied. The X-ray diffraction patterns indicated that the synthesized samples with a mole fraction of Tb3+ doping of 0.17% possessed a monoclinic structure. The excitation spectra of the resultant phosphor exhibited a continuous luminescence band with a peak position near to 345 nm and its emission spectra had a peak nearby 510 nm. For the intensity decay curves, the afterglow properties could be modified by Tb3+ suitably doping. Comparing to SrAl2O4:Eu2+,Dy3+ phosphor, the doped Tb3+ favored the solid solution with a good crystalline, and the crystals in the sample were fine and compact and had an average diameter of 100 nm. Key words: combustion; long persistence phosphor; europium; dysprosium; strontium aluminate; terbium doping 随着经济的高速发展，人们对环保的意识得以加强，因而环保、节能的绿色材料也越来越受到人们的关注，而长余辉发光材料就是一种储能、节能的光致发光“绿色”材料，它能把吸收的自然光等储存起来，在较暗的环境中呈现出明亮的可见光，具有指示照明和装饰照明的作用，有非常广泛的应用前景。传统硫化物发光体在空气中容易被氧化，化学稳定性差，亮度低，在应用中受到很大限制，已逐步被淘汰[1]。近年来，铝酸锶长余辉发光材料因其发光效率高，余辉性能好，稳定性强