全钒液流电池复合材料双极板研究 - 高校化学工程学报.pdf

第25 卷第2 期 高 校 化 学 工 程 学 报 No.2 Vol.25 2011 年 4 月 Journal of Chemical Engineering of Chinese Universities Apr. 2011  文章编号：1003-9015(2011)02-0308-06 全钒液流电池复合材料双极板研究 徐冬清, 范永生, 刘 平, 王保国 (清华大学 化学工程系, 北京 100084) 摘 要：研究导电性高、耐腐蚀性强的双极板对发展全钒液流电池等大规模蓄电储能装备具有重要意义。在聚偏氟乙 烯(PVDF)高分子基体中加入炭黑(CB)、鳞片石墨(GP)、膨胀石墨(EG)等导电填料，均匀分散后制备导电双极板，考察 了导电填料种类、含量、粒度大小、分散方式对双极板导电性能的影响规律，利用Ｘ射线衍射(XRD)和扫描电子显微 镜(SEM)表征导电填料本体和微观分散形态。结果表明使用粒径较小的可膨胀石墨有利于提高导电率，溶解法和悬浮 液法均能保证导电填料的良好分散，所制备的双极板具有相近的导电性能，但后者易于进行大规模工业化生产。使用 400 目可膨胀石墨为导电填料制作双极板，当其质量含量为50%时，电导率达到92 S⋅cm− 1 ，弯曲强度为52 MPa 。所研 究的导电塑料双极板能够完全阻隔钒离子渗透，具有良好抗氧化性能，有望在全钒液流电池的实际开发过程中应用。 关键词：液流电池；双极板；复合材料；电导率 中图分类号：TM911.49 ；TM912.1 文献标识码：A Research of Composite Bipolar Plate Used for Vanadium Redox Flow Battery XU Dong-qing, FAN Yong-sheng, LIU Ping, WANG Bao-guo (Department of Chemical Engineering, Tsinghua University, Beijing 100084, China) Abstract: Development of a bipolar plate with high conductivity and good antioxidant ability is significant for the vanadium redox flow battery (VRB) and other mass electricity storage equipments. Conductive plastic plate can be made by adding conductive fillers, such as carbon black (CB), graphite (GP), and expandable graphite (EG), into polymer matrixes. This study investigated the influences of different conductive fillers and their compositions, size, distribution method on the conductivity of the prepared bipolar plate, besides, the XRD and SEM were used to characterize the fillers and their morphologies in polymer matrixes. The filler paticles with smaller size is benefit for its distribution to improve conductivity, and the