晶化温度对sapo-34 结构稳定性的影响effect of crystallization .pdf

2008 年第66 卷 化 学 学 报 Vol. 66, 2008 第11 期, 1317～1321 ACTA CHIMICA SINICA No. 11, 1317～1321 ·研究论文· 晶化温度对 SAPO-34 结构稳定性的影响 王利军*,a 赵海涛b 郝志显b 徐立陆b 解丽丽a 田 震a 袁 昊a 邴乃慈a 李庆华a (a 上海第二工业大学城市建设与环境工程学院 上海 201209) (b 同济大学化学系 上海 200092) 摘要 用二乙胺结构导向剂, 分别在473 和573 K 水热晶化得到两种SAPO-34 分子筛材料. SEM 和XRD 结果表明, 晶 化温度升高, SAPO-34 晶粒增大, 结晶度提高, 比表面积和孔径增大. 升高晶化温度, 提高了样品的最高焙烧和水蒸汽 热处理承受温度. 关键词 二乙胺; 水热法; SAPO-34; 焙烧; 水蒸汽热处理 Effect of Crystallization Temperature on SAPO-34 Structure Stability WANG, Li-Jun*,a ZHAO, Hai-Taob HAO, Zhi-Xianb XU, Li-Lub XIE, Li-Lia TIAN, Zhena YUAN, Haoa BING, Nai-Cia LI, Qing-Huaa a ( School of Urban Development and Environmental Engineering, Shanghai Second Polytechnic University, Shanghai 201209) (b Department of Chemistry, Tongji University, Shanghai 200092) Abstract Two SAPO-34 samples were hydrothermally synthesized at 473 and 573 K respectively with di- ethylamine as the structure-director. SEM and XRD results showed that the SAPO-34 crystal size, crystallin- ity, BET surface area and pore diameter increased with increasing the crystallization temperature. The high- est permissible calcination temperature and the highest permissible steam treatment temperature increased with increasing the crystallization temperature. Keywords diethylamine; hydrothermal method; SAPO-34; calcination; steam treatment [1] 导向剂, 探索在新条件