机械剥离法大量制备石墨烯及其在复合材料中的应用.pdfVIP

机械剥离法大量制备石墨烯及其在复合材料中的应用 陈国华，赵卫峰 （华侨大学材料科学与工程学院，福建厦门 361021 ） 摘要：如何低成本、高效率、大批量制备具有较好晶体结构的石墨烯产品是目前石墨烯研究领域的重要课题。本 文提出了采用已被广泛应用于实际生产的球磨法对石墨进行机械剥离制备石墨烯。在磨球剪切力作用下, 通过湿 法球磨，可以有效的将石墨片剥离成单层及寡数层石墨烯。本研究以DMF 和水作为研磨介质，分别利用篮式研 磨机对石墨烯的制备工艺进行初步放大。石墨的投料量由行星式球磨时的0.02 g 提高到搅拌研磨的20g，放大了 1-00 倍之多。结果表明，篮式研磨能实现对较多量石墨片进行层层剥离，制备出单层以及寡数层石墨烯产品。利 用石墨烯与高分子的复合，可以得到较低导电渗滤值的复合材料。 关键词：石墨烯；球磨剥离法；复合材料 Scaled Preparation of Graphene Via Mechanical Exfoliation and Applications in Composites CHEN Guohua, ZHAO Weifeng (Material Science Engineering College, Huaqiao University, Xiamen, 361021, China) Abstracts ：In this study, ball milling was suggested for the first time to peel graphite flake off for graphene production. As a common industrial technique, the ball milling method possess many advantages such as it is convenient for operation, and can be easily scaled up into mass production, making it holds great promise to become a realizable way for the scale production of graphene.By using the shear forces applied by the milling balls in a in a planetary mill operated at a low speed, graphite was peeled off mechanically to produce graphene in N,N-dimethylformamide(DMF). The graphene products were identified and characterized using transmission and scanning electron microscopy, electron diffraction, atomic force microscopy and Raman spectroscopy. The results indicate that, wet ball milling is a reliable route to exfoliate graphite into graphene, single- and few-layer graphene sheets have been successfully prepared. Keywords ：Graphene, Mechanical Exfoliation, Composites 1 前言 [1] 2004 年安德烈·盖姆（Geim）研究组 利用“胶带法”成功制备了石墨烯并在《科学》上发表了石墨烯的 特异性质的