多壁碳纳米管负载铂的甲苯加氢脱芳催化剂pdf.PDF

28 3 2007 3 Vol. 28 No. 3 Chinese Journal of Catalysis March 2007 :2007 : 210~ 216 周 敏, 林国栋, 张鸿斌 (厦门大学化学化工学院固体表面物理化学国家重点实验室, 福建厦门361005) : ( CNTs) Pt Pt/ CNTs (HDA) . , 10%Pt/CNTs , 04 MPa, 373 K, PhCH /H = 6/94GHSV= 120 L/ (hg) , 3 2 2 100%, 0052 3 mmol/ (sm ) , Al O AC Pt 14% Pt/ 2 3 Al O 24%Pt/AC 117 118. , 2 3 . , CNTsAl O AC Pt HDA 2 3 . Al O AC ,, CNTs Pt 2 3 0 , Pt ( Pt ) Pt ; , CNTsPt H2 /. HDA . : ; ; ; ; : O643/TQ53 : A Pt Catalyst Supported on Multiwalled Carbon Nanotubes for HydrogenationDearomatization of Toluene ZHOU Min, LIN Guodong, ZHANG Hongbin* ( State K ey L aboratory of Physical Chemistry of Solid Surf aces, College of Chemistry and Chemical Engineering , Xiamen University, Xiamen 36 005 , Fuj ian, China) Abstract: Using homemade multiwalled carbon nanotubes (CNTs) as the support, the Pt/CNTs catalyst was preparedby an incipient wetness method. Performanceof thecatalyst for hydrogenationdearomatization (HDA) of toluene was evaluated and compared with the reference catalysts supported on Al O and activated carbon 2 3 (AC). Over the 10%Pt/CNTs catalyst under the reaction conditions of 04 MPa, 373 K, PhCH /H = 6/94