动力锂离子电池隔膜的研究进展_孙美玲.pdfVIP

44 材料导报A : 综述篇 2011 年5 月( 上) 第25 卷第5 期 * 孙美玲, 唐浩林, 潘 牧 ( , 430070) 从孔隙率浸润性强度热尺寸稳定性热关闭温度和热熔化温度评述了 离子电池隔膜的研究进展, 认为平衡并同时提高隔膜的性能和安全性是动力 电池隔膜重要的研究方向目前, 采用接枝官能基团以及添加亲 水物质的方法可以改善膜的浸润性; 不同熔点的聚合物复合以及采用高结晶度聚合物均可改善隔膜的热关闭温度和 热熔化温度采用 一种多孔基体材料, 如无纺布或电纺纤维作为增强基体, 可以保证膜的强度尺寸稳定性和热熔化 温度; 采用其它的聚合物作为成孔材料, 可以改善膜的孔隙率和浸润性, 是同时提高隔膜的性能和安全性的有效手段 A Revi ew on the Separators of Power Lii on Batteries SU N M eiling, T ANG Haolin, PAN M u ( Stat e K ey L abo ato y of Advanced T echno lo gy fo M ate ials Synthesis and P ocessing , W uhan U nive sity of T echno lo gy , Wuhan 430070) Abstract T he p o g ess of the po o sity, w et tabilit y, mechanical st ength, the mally dimensio nal stability, shutdow n as w ell as meltdow n tempe atu e of sepa ato towa ds L i io n batte y is summa ized. T he esults sug gest that the wettability can be imp ov ed by g afting functio nal g o ups o adding hyd o philic o x ides. U sing po ly me mix tu es w it h diffe ent g lass t ansitio n tempe atu es, as w ell as using polyme s w ith hig h c ystallinity can imp ov e the shutdow n and meltdow n tempe atu es of the sepa ato s. Fo the po o sity, punctu e st ength and t he mally dimensio n al stability, the p omising o ute is fo und t o be using a po o us po ly me as the einfo cement t o imp o ve the mechanical st ength, the mall dimensio na l stability and shutdown tempe atu e, and using anothe po ly me as the po efo me to imp o ve the po o sity and w ettability . Key words L i ion powe bat te y, sepa ato , po osity , w ettability, shutdow n and meltdown tempe atu es