本研究主要以聚对苯二甲酸乙二醇酯（PET）和聚醯胺6(PA.PDFVIP

摘要 本研究主要以聚對苯二甲酸乙二醇酯(PET)與聚醯胺6(PA 6, 商品名 為Nylon 6 ）為基材，木粉為添加材來製備圕木複材。兩種圕料基(PET/ Nylon 6)之摻混比例分別為 60/40 、50/50和 40/60 。在固定木粉添加量後，分別探 討添加聚烯烴彈性體接枝馬來酸酐 (POEgMA)或甲基丙烯酸酯 -丁二烯-苯 乙烯(MBS)此兩種改質劑對圕木複材機械性質的影響，接著並探討在不同 溫濕老化、溫濕效應與加速風化試驗下對其機械性質的影響。 研究結果顯示，圕木複材經過 30 天之溫濕老化與加速風化測試後，不 論添加 POEgMA或 MBS ，其拉伸強度、彎曲強度與彎曲模數在高溫高濕 條件下 (55℃/90RH%)損失量最大，且加速風化 30 天後皆有下降的趨勢；並 且由於 Nylon 6吸濕增韌的作用，反而使得在高溫高濕下其衝擊強度有提 升的效果。然而加速風化環境對於圕木複材的影響，不僅造成機械性質的 改變，也因為光降解與吸濕作用導致圕木複材產生表面顏色之變化；複材 潛變研究方面，圕木複材之應變量皆隨溫濕環境提升或是應力增加而提 升。 關鍵字 : WPC 、溫濕老化、加速風化 、機械性質 I Abstract Concern for the environment, both in term of limiting the use of finite resources and the need to manage waste disposal, one of the rising environment protection materials is wood plastic composites(WPC). The study investigates the feasibility of using recycle Nylon6, Poly(ethylene terephthalate) and wood flour to manufacture experimental composite specimens. The specimens were made through extrusion, pelletised and injection molding. By adding POE-g-MA as agent into PET/Nylon (60/40 、50/50、40/60), and MBS as impact- resistant agent into PET/Nylon (60/40 、50/50 、40/60), then discuss mechanical properties of WPC under different thermal and humid aging, thermal and humid effect and accelerate weathering. After thermal and humid aging for 200 hours and then accelerate weathering for one month, the result showed that no matter add POE-g-MA or MBS in the WPC, its tensile strength, flexure strength an d flexure modulus will lose the biggest amount in the 55℃/90RH%. After accelerate weathering for one month, the result showed a decreasing trend. Besides, the impact strength in the 55℃/90RH% will enhance because the moisture absorption of Nylon6