工业催化结业论文概要1.doc

南京工业大学 研究生催化研究进展 课程试题（考试/考查） 2014 - 2015 学年 第 2 学期 班级 化学工程3班 学号 姓名 贾广楼 催化剂脱氢制备邻苯二酚的研究 姓名：贾广楼a,b 专业：化学工程 学号（a南京工业大学；b盐城师范学院 ） 摘 要 邻苯二酚是重要有机中间体,也可用于生产阻聚剂、染料、医药、防腐剂等，国内对其需求很大，但主要依赖于进口。因此有必要对邻苯二酚的合成方法进行研究，其合成方法主要有邻氯苯酚碱性水解法、苯酚羟基化法、1,2-环己二醇脱氢法等。环己二醇脱氢制备邻苯二酚关键在于研制高稳定性、高活性和高选择性的脱氢催化剂，当前环己二醇脱氢催化剂的研究多以Pd和Ni为活性组分的催化剂为主。这些催化剂的单程使用寿命普遍较短,需要频繁的连续再生,不利于工业化生产,因而需要对脱氢催化剂做进一步的研究。本文主要综述了环己二醇脱氢催化剂的研究展。由文献可知活性较好的脱氢催化剂有Pd、Pt、Ni等，以活性炭为载体，用普通浸渍法制成的催化剂效果较好。 环己二醇脱氢 催化剂 活性炭Abstract Pyrocatechol is an important organic intermediates, and can be used in the production of inhibitor, dye, medicine, preservative, etc., because of its domestic demand is very big, but mainly rely on imports. So it is necessary to study the synthetic methods of pyrocatechol, its synthetic methods mainly include o-chlorophenol alkaline hydrolysis, phenol hydroxylation, 1, 2 - cyclohexanol diol dehydrogenation method, etc. Cyclohexanol diol preparing catechol dehydrogenation is the key to development of high stability, high selectivity and high dehydrogenation catalysts, the current research of cyclohexanol diol dehydrogenation catalyst is given priority to with Pd and Ni as the active component of catalyst. One-way service life of the catalyst is generally short, need frequent continuous regeneration, unfavorable to industrialized production, and therefore need to make further research in the dehydrogenation catalyst. This article mainly reviews the cyclohexanol diol dehydrogenation catalyst research show. By literature shows active better dehydrogenation catalysts such as Pd, Pt, Ni, with activated carbon as the carrier, using ordinary impregnation method into the catalyst effect is better. 【key words】 Catechol cyclohexanol Diol dehydrogenation Catalyst Activated carbon 第一章 前 言 1.1 邻苯二酚的概述 1,2-环己二醇催化脱氢法制备邻苯二酚最早由Paushkin等[1]在20世纪70年代提出。日本、原苏联以及中国的一些学者对1,2-环己二醇脱氢制备邻苯二酚所用脱氢催化剂进行了大量的研究。70年代，原苏联Sarylova等[2]制备了一系列含不同金属元素的Pd-M脱氢催化剂：①1％Ni，②5％Ti，⑧8％Cu，④37％Cu，5)40%Cu，⑥42％Cu，⑦7％Rh，⑧