铁-镧系合金氧化物污水除磷及再生研究 - 环境工程学报.docVIP

铁-镧系合金氧化物污水除磷及再生研究 杨永珠1 江映翔1 赵李丽1 刘艳冰2 （1.昆明理工大学环境科学与工程学院，昆明 650093； 2.云南碧蓝环境工程有限公司，昆明 650034） 摘 要 采用共沉淀法制备了系列铁-镧系合金氧化物并研究其除磷能力。结果表明：以铁、镧摩尔比为0.08的吸附剂除磷能力最强，吸附曲线适合Langmuir等温线方程。该吸附剂的吸附量受pH影响显著，pH在4.0~7.0之间时吸附量较大。进行了抗共存阴离子能力测试，结果表明CO32-对磷吸附量影响较大，给出了共存阴离子对吸附量的影响顺序。对该吸附剂进行了真空高温再生，再生率最高可达62.27%。 关键词 铁-镧系合金氧化物 除磷 吸附 再生 中图分类号：TQ424.29 Study on phosphorous removal from wastewater by the iron- lanthanum based alloy oxides and their regeneration Yang Yongzhu 1 Jiang Yingxiang1 Zhao Lili1 Liu Yanbing2 (1.Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China; 2. Yunnan Blue Company of Environmental Engineering, Kunming 650034, China)  Abstract A series of iron - lanthanum based alloy oxides were developed by co-precipitation method and investigated their ability to remove phosphate. Test results indicated the absorbent achieved the highest absorptional capacity under the iron-lanthanum mole ratio of 0.08 . It was proved that the absorptional curve was confined to Langmuir isotherm equation. The absorptional volume of the absorbent was significantly influenced by pH. The absorptional volume achieved the maxima at the pH range from 4.0 to 7.0. The paper also studied the influences of co-existed anions on the absorptional capacity. The phosphorous absorptional capacity was greatly influenced by the carbonate ion and the influential sequence of the co-existing ions on the absorptional capacity was given. The absorbent was regenerated by a high-temperature vacuum calcining method and the highest regeneration rate was 62.27%. Keywords iron - lanthanum based alloy oxides; phosphorous removal; adsorption; regeneration 磷是引起水体富营养化的主要元素之一[1]，对废水中磷的去除受到越来越多的关注。目前处理含磷废水的方法主要有化学沉淀法、生物法以及吸附法。吸附法具有设备简单、运行可靠，同时能够回收利用磷资源、不产生二次污染等优点[2]。选用价格低廉、材料易得、制备简单、吸附量大、再生容易的吸附剂是研究者关注的重点。国内外研究得比较多的有天然物质[3-4]、工业废渣[5-6]以及一些人工合成材料[7-8]。稀土氧化物由于对磷酸根离子有选择吸附性而受到了较高的关注[9-12]。本研究采用共沉淀法[13]制备了铁-镧系合金吸附剂，同时研究了铁-镧系合金吸附剂对磷的吸附性能，并对吸附剂进