微波消解-原子荧光光谱法测定7种化妆品中汞和砷含量.pdfVIP

·药物鉴定­ 2013 年 7 月 20 日第22 卷第 14 期 f t到~~ Drug Idenfification China Pharmaceuticals VoL 22 ,No. 12,July 20, 2013 微波消解 E子荧血血谱注调定7 神1临口中墨和耐含量 4 用平 - b7.T~7lï7lï厢1Z4 i.则~ 伊rlLlU(.目目甲凉11甲画[呈 迟少云，王尊文，莫琦 (山东省青岛市药品检验所，山东青岛 266071) 摘要:目的测定7 种化妆品中采和碎的含量。方法采用微波消解系统消化样品，用原子荧光光谱仪测定含量。结果系和碎的检出限 分别为 0.023 问IL 和 0.036μg/L ，精密度的 RSD 分别为 0.7% 和1. 1% ，平均回收率分别为 97.399岛和 96.919岛。结论微波消解­ 原子荧光光谱法具有操作简便、准确、灵敏、重现性好等优点，可用于化妆品中系和碎的含量测定。 关键词:微波消解;原子荧光光谱法;化妆品;呆:种 中图分类号:R927.11 文献标识码:A 文章编号: 1006 - 493 1(2013 )14 - 0058 - 02 Determination of Mercury and Arsenic in Seven Kinds of Cosmetics by Microwave Digestion - Atomic Fluorescence Spectrometry Chi Shωyun ， Wang Zunwen , Xi Wei (Qingdao Municipal Institute for Drug Control , Qingdao , Shandong , China 266071) Abs仕act:Objective To detennine the contents of mercury and arsenic in seven kinds of cosmetics. Methods The mercuηand arsenic contents in the sample were detennined by the atomic fluorescence spectrometry after digestion by microwave. Results The detection limits of mercury and arsenic we陀 0.023μg/L and 0.036μg/L， the relative stangard deviations( RSD) were 0.7% and 1. 1 % , and the average recoverγrates were 97.39% and 96.91 % , respectively. Conclution The microwave digestion - atomic fluorescence spec- trometry method has the advantages of simple operation , accuracy , high sensitivity and good repeatability ,which can be used for the de- tennination of mercury and arsenic in cosmetics. Key words: microwave digestion; atomic fluorescence spectrometry; cosmetics; mercury; arsenic 柔和碑是具有蓄积性的有毒元素，因此化妆品卫生规范中其