应用自制的自动化测定仪-流动注射-光纤光谱法测定纺织品中甲醛含量.pdfVIP

PTCA(PART B: CHEM. ANA L.) 001: 10. 11973/lhjy-hx201511008 |工.1乍简报 应用自制的自动化测定仪-流动注射-光纤 光谱法测定纺织品中甲醒含量 江涛，倪鹏，张晓冬，施锦辉，洪华，申晓萍，侯晋 (南通出入境检验检疫局，南通 226000) 摘要:用自制的自动化测定仪流动注射光纤吸收光谱仪测定了纺织品中甲酶的含量。甲醒 与乙眈丙嗣的显色反应在流动注射体系完成，乙耽丙画同的体积分数为 0.5% ，反应温度为 80 C ，在 最大吸收波长 414 nm 处测量体系的吸光度。甲醒的质量浓度在 O. 025~3. 00 mg. L-] 范围内与 其吸光度呈线性关系，方法的检出限C3S/N) 为 0.025 mg L-] 。对1. 00 mg • L-] 甲醒标准溶液 连续测定 10 次，相对标准偏差为 0.95% 。方法应用于纺织品样品的分析，测定结果与国标法测定 值相符.回收率在 96. 5%~117%之间。 关键词:流动注射;光纤光谱法;甲醒;纺织品 中图分类号: 0657.32 文献标志码:A 文章编号: 1001-4020(201日1 1-1 524-05 FI-Spectrometric Determination of Formaldehyde in Textiles with a Self-Made Automatic Analyzer JIANG Tao , NI Peng , ZHANG Xia~dong， SHI Jin-hui , HONG Hua , SHEN Xia~ping， HOU Jin (飞[untmlg Entr;rE.rit lns户ectiulI und Quarantine Bureau , Nantong 226000 , China) Abstract: 八 self-made FI-fiber-absorption spectrometric automatic analyzer was applied to the determination of formaldehydc in textiles. The color-reaction of formaldehyde with acetylacetone was completed in the flow l 叼ection system. with (w) O. 5% of acetylaceton and at 80 C. The absorbance of the color system was measured at its maximum absorption wavelength of 414 nm. Linear relationship between values of absorbance and mass concentration of formanldehyde was obtained in the range of O. 025-3. 00 mg L一 1 , with detection Iimit (3S/N) of O. 025 mg • L-1. Precision of the method was tested at the concentration level of 1. 00 mg • L-1 formanldehyde standard solution for 10 detcrmination , value of RSD found was O. 95%. The proposed method was applied to the analysis of textil