气质联用法测定洋葱中有机磷类及拟除虫菊酯类农药残留量.pdfVIP

ofAnhui 安徽农业科学。Journal Agri．Sci．2011。39(6)：3327-3329 责任编辑郑丹丹责任校对马君叶 气质联用法测定洋葱中有机磷类及拟除虫菊酯类农药残留量 邵辉，张玉婷，刘磊，李娜，李辉，宋淑荣，郭永泽+ (天津市农业科学院中心实验室，：天津300192) 摘要[目的]为监测洋葱中有机磷类及拟除虫菊酯类农药提供技术支持。[方法]采用添加回收的方法对洋葱中农药提取和杂质去除 方式进行摸索。[结果]建立了洋葱中有机磷类及拟除虫菊酯类农药残留量气质联用测定方法。方法添加浓度为0．10和0．01mr／kg， 平均回收率为73．9％一109．9％，相对标准偏差为1．49％一11．20％。检出限为0．002—0．010mg／ks。[结论]建立的方法灵敏度高，集准 确定性与定量于一体，为去除洋葱中农药残留测定时硫化物的干扰提供了新途径。 关键词 气质联用；测定；洋葱；有机磷类农药；拟除虫菊酯类农药 中图分类号s481．．8文献标识码A 文章编号0517—66II(2011)06—03327—03 of in DeterminationoftheResiduethe and PesticideOnionGC·MS OTglmicPhosphorusPyrethroid by sIIAoHllietm of (CentralLaboratory．TianjinAcademyAgriculturalSciences．Tianjin300192) technicalfortIletestofthe and intheonionwas Abstract[Objective]11lesupport organophosphatepyrethroidpesticides provided．[Method] The ofthe inonionandthe fromit basedOilthe ofaddition extractionmethodagro．ehemicMcomponent were technique impurity．removalexplored and methodof for ofthe and intheon- GC—MSwasestablishedthe recovery．[Result]11le residue-testingorganophosphatepyrethroidpesticides i11the and jo／1．The concentrationmethodWas0．10 0．01 relativestandarddevl— adding Ill{∥kg。theaveragerecoveryw鼬73．9％一109．9％，the and ation detectionlimitWas0．002—0．010 ThemethodWassensitive the w∞1．49％一11．20％。the we．／虹．[Conclusion accurate，withsyn- chronouscharacterof and anewremovalofthesulfideinterferenceinthedeterminationof q