添加少量ta 及热机处理对fe-mn-si 基形状记忆合金性质影响 - yoke.pdf

添加少量Ta 及熱機處理對Fe-Mn-Si 基形狀記憶合金性質 影響之研究 Effect of slight tantalum addition and thermo-mechanical treatment on Fe–Mn–Si shape memory alloy 楊政修* 林新智 林昆明1 C.H. Yang*, H.C. Lin, K.M. Lin1 國立台灣大學材料科學與工程學系 1 逢甲大學材料科學與工程學系 摘要 本研究以真空電弧熔煉爐(VAR)熔煉Fe-30Mn-6Si 及Fe-30Mn-6Si-0.4Ta 合金，經 1100°C 之熱加工後，再於1150°C 固溶/退火處理 1 小時。之後分別經過不同熱處 理及熱機處理後，針對其顯微結構、析出行為、機械性質、變態溫度及形狀記憶 特性做有系統之探討。實驗結果顯示添加少量Ta 會稍微增加ε martensite 的c/a 值、降低 Ms 溫度並增進形狀回復率。經過適當的熱機處理(TMT)後由於整齊排 列的D03 相及TaC 的析出效應可更進一步提升形狀回復率。 關鍵詞：形狀記憶合金、熱機處理、D03 、TaC Abstract The Fe-30Mn-6Si and Fe-30Mn-6Si-0.4Ta (wt.%) alloys were prepared by an arc remelting furnace. The as-cast ingot was hot-rolled into a plate with 2 mm-thickness at 1100 ºC, solution treated at 1150ºC for 1 hour and water quenched. The specimens were then subjected to various heat and thermo-mechanical treatment (TMT) conditions. The effects of slight tantalum addition and TMT on Fe-30Mn-6Si shape memory alloy were investigated, including the microstructure, precipitation behavior, mechanical properties, transformation temperature and shape memory performance. Experimental results show that the slight Ta addition will increase the c/a ratio of ε martensite, reduce the Ms temperature and improve the alloy’s shape recovery ability. After TMT at 650°C, well-aligned D03 phase and TaC precipitates within the grain interior indeed improve the alloy’s shape memory performance. Keywords: shape memory alloy, thermo-mechanical treatment, D0 , TaC. 3 前言 在所有的形狀記憶合金中，Fe-Mn-Si-based 形狀記憶合金由於它的價格低、 具良好的機械性質、加工性及焊接性使其在工程的應用潛力上受到重視。但由於 其形狀回復率甚低於Ni–Ti-based 合金 使得應用上受到限制。然而，經由合金設 (1)(2)(3)(4)(5) (6)(7)(8)(9)(10)(11)(12)