铜卟啉合成及其敏化二氧化钛光催化剂的制备 - 大学化学.pdf

大学化学(Daxue Huaxue) 46 Univ. Chem. 2017, 32 (4), 46－51 April ∙化学实验∙ doi: 10.3866/PKU.DXHX201609027 铜卟啉合成及其敏化二氧化钛光催化剂的制备 ——一个大学化学综合性实验 南志祥 李 珺* 张逢星 白银娟 (西北大学化学与材料科学学院，合成与天然功能分子化学教育部重点实验室，西安710127) 摘要：介绍了一个大学化学综合性实验——铜卟啉合成及其敏化二氧化钛光催化剂的制备。该实验是一 个科研转化的大学生综合化学实验，内容包括铜四苯基卟啉的合成、铜四苯基卟啉敏化二氧化钛光催化 剂的制备，以及光催化剂对水中有机污染物的降解。通过本实验，可以拓宽学生的化学专业知识，提高 学生的综合实验操作技能，激发学生对科学研究的兴趣，培养学生的科研探究能力。 关键词：铜卟啉；二氧化钛；光催化剂；光降解；综合化学实验 中图分类号：G64 ；O6 Preparation of TiO2 Photocatalyst Sensitized by Copper(II) Porphyrin: A College Comprehensive Chemical Experiment NAN Zhi-Xiang LI Jun* ZHANG Feng-Xing BAI Yin-Juan (Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xian 710127, P. R. China) Abstract: A new college comprehensive chemical experiment, preparation of TiO2 photocatalyst sensitized by copper(II) porphyrin, was developed. The experiment is from the achievements of scientific research. It includes the synthesis of copper(II) tetraphenyl porphyrin, the preparation of TiO photocatalyst 2 sensitized by copper(II) tetraphenyl porphyrin, and photodegradation of organic contaminant in water. Throughtheexperimentalprocess,students′chemicalknowledgewillbeexpanded,andchemical experimentskillwillbeimproved.Furthermore,students′interestinscientificresearchcanbestimulated and cultivated. Key Words: Copper(II) porphyrin; Titanium dioxide; Photocatalyst; Photodegradation;