低温溶胶法制备钨、氮共掺杂二氧化钛光催化剂的研究 - 钢铁钒钛.pdf

第34卷第5期 钢摇 铁摇 钒摇 钛 Vol郾34,No郾5 2013年10月 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 IRON STEEL VANADIUM TITANIUM 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 October2013 低温溶胶法制备钨、氮共掺杂二氧化钛 光催化剂的研究 孟摇 波,王晓晶,李摇 雪,刘云义 ( 沈阳化工大学化学工程学院,辽宁省化工应用技术重点实验室,辽宁沈阳110142) 摘摇 要:以钛酸四正丁酯为前驱体,硝酸铵和钨酸铵为掺杂源,利用低温溶胶法直接制备了纳米级钨、氮共掺杂二 氧化钛粉体。 通过XRD、SEM、IR、XPS、GTA等测试手段对样品进行表征,结果表明:共掺杂TiO 粉体为锐钛矿型, 2 呈球状颗粒,粒径为8.9 nm,600 益内稳定性好,禁带宽度2.86 eV,光响应迁移到可见光范围。 以氙灯模拟太阳光 降解甲基橙溶液,光照60 min,光催化剂粉体的降解率达到94%以上,与P25相比有明显提高,具有良好的光降解 性能。 关键词:低温溶胶;二氧化钛;光催化;共掺杂 中图分类号:TF841郾3,TQ426摇 摇 文献标志码:A摇 摇 文章编号:1004-7638(2013)05-0023-05 DOI:10.7513/ j.issn.1004-7638.2013.05.005 Study on Preparation of W,N Codoped TiO Photocatalyst 2 by Low鄄temperature Sol Process Meng Bo,Wang Xiaojing,Li Xue,Liu Yunyi (School of Chemical Engineering,Shenyang University of Chemical Technology,Shenyang ,Shenyang 110142,Liaoning, China) Abstract:Takingtetra鄄n鄄butyltitanateasprecursorandammoniumnitrateandammoniumtungstateasco鄄 doping sources, nanoscale W, N codoped TiO powder is directly prepared by low鄄temperature sol 2 process. The samples are characterized by XRD,SEM,IR,XPS,and GTA. The results show that the spherical codoped photocatalyst powder is anatase TiO with particle sizes of 8.9 nm and good stability 2 below600 益;theenergy gap of thepowder is2.86 eV andthephotoresponsemovestotherangeof visi鄄 ble light. Sunlight isreplacedby xenonlamp to degrade methyl oran