na 添加 mg 2si の热电特性 - j-stage.pdf

日本金属学会誌第 巻 第 号( )  72 9 2008 693 697 Na 添加Mg Si の熱電特性 2 1, 1 1, 2 1 丹羽陽亮  戸高義一  梅本　実 山名啓太2 木下恭一2 谷澤元治2 1豊橋技術大学生産システム工学系 2株式会社豊田自動織機 ( )  J. Japan Inst. Metals, Vol. 72, No. 9 2008 , pp. 693 697 2008 The Japan Institute of Metals  Thermoelectric Property of Na Doped Mg Si 2 1, 1 1, 2 1   Yosuke Niwa , Yoshikazu Todaka , Minoru Umemoto , Keita Yamana2 , Kyoichi Kinoshita2 and Motoharu Tanizawa2 1  Department of Production System Engineering, Toyohashi University of Technology, Toyohashi 441 8580 2  TOYOTA INDUSTRIES CORPORATION, Obu 474 8601  First principles calculation revealed that Na atoms were expected to be primarily located Mg sites in Mg Si. Densities of 2     electronic states of the Na doped Mg Si showed p type. To obtain a good p type thermoelectric material, Na doped Mg Si 2 2 ( )   Mg － Si Na were fabricated by solid liquid reaction using spark plasma sintering. The X ray diffracti