电性能分析.doc

Facile synthesis and electrochemical properties of CoMn2O4anodes for high capacity lithium-ion batteries CoMn2O4Spinel Hierarchical Microspheres Assembled with Porous Nanosheets as Stable Anodes for Lithium-ion Batteries Figure 5b shows discharge-charge curves of the electrodes made from the CoMn2O4 hierarchical microspheres at a current density of 100 mA·g-1 at room temperature in a potential window between 0.01 and 3.0 V (vs. Li+/Li). It can be seen that there is a large deviation in potential between charge and discharge curves. The gap between charge and discharge curves is important, which involves the energy efficiency. The large gap may be a feature of metal oxide anode due to the polarization related to ion transfer during charge-discharge cycles. This phenomenon is often observed in many metal oxide anodes due to poor electrical conductivity, including CoMn2O4 reported previously. It is reported that the incorporation of graphene sheets can partly reduce the voltage polarization. The solution can be further studied in the future. The initial discharge and charge capacities are 1442 and 937 mAh g-1, which is higher than the theoretical value (920mAh g-1) based on the conversion reaction (see equation 5). The excess capacities could be associated with the decomposition of the electrolyte at low voltages generating a solid electrolyte interphase (SEI) layer and the further lithium storage via interfacial charging at the metal/Li2O interface. The large irreversible capacity loss of the first cycle can be attributed to the phenomenon that the formed SEI film can not completely decompose during the first charge. Figure 5c shows the discharge/charge capacity versus cycle number for the electrodes made from the CoMn2O4 hierarchical microspheres at a current of 100 mAh g-1. It is interesting to observe that the discharge capacity decreases only slightly before 36 cycles. After that, more interestingly, an unusual phenomenon that the discharge capacity gradually