应用电化学概要1.pptVIP

Chapter 2  Electrochemical  Engineering 应用电化学考核方式 平时作业: 7次作业（每章一次），14分 课堂考勤8分（班干部负责）： 16次课，每次0.5分。扣分项：旷课0.5分，迟到0.2，请假0.1 大型作业（文献或研究报告）：分组做课堂报告1次，28分 评定方法：小组分：满分（28*人数），由教师评定小组分，然后由各小组评定个人得分 本章教学目的与要求 2.1 General consideration 2.2 Performance and figures of merit 2.3 Optimization and Electrolysis parameters 2.4 Mass transport and heat transfer 2.5??Potential distribution current distribution 2.6 Electrochemical Reactors/cells 2.1 General consideration Electrochemical engineering is the science which considers design and operation of electrochemical processes under optimum technological and economic conditions. 如何进行技术评价？——技术指标 where 1 mole of the reactant A receives n moles of electrons to yield np moles of product P. Optimization of electrochemical processes 2.4 Mass transport and heat transfer Mass transport in industrial electrolysis In most, the flow is too complex to warrant a detailed fluid-mechanical calculation. Rather, the normal approach to mass transport in electrolysis cells is to treat the cell as a unified whole and to seek expressions in term of space-averaged quantities . In general, mass transport in electrolysis cells with flow may be discussed in terms of the expression (dimensionless parameters equation): c) Schmidt number Sc Heat transport 2.5????? Potential distribution and current distribution 1. Factors influencing current distribution 2. Three types of current distribution 3.? Simple treatment of current distribution 4.?? Similarity theory and current distribution 2.5.1 Factors influencing current distribution The current distribution is a function of the local concentration of electroactive species as well as the potential distribution. The potential distribution will depend on the relative positions of the anode and cathode and their surface profiles. The current distribution is related closely to tha