第2章化学反应进行的方向及热力学初步.pptVIP

CaCO3(s) ? CaO(s) + CO2(g) ?H? = ? CaCO3(s) ? Ca(s) + C(s) + 3/2 O2(g) ?H1 = ?ΔfH?[CaCO3(s)] = 1207.6 kJ (1) C(s) + O2(g) ? CO2(g) ?H2 = ΔfH?[CO2(g)] = ?393.5 kJ (2) Ca(s) + ? O2(g) ? CaO(s) ?H3 = ΔfH?[CaO(s)] = ?635.0 kJ (3) (1) + (2) + (3) ? ?H? = ?H1 + ?H2 + ?H3 = ?ΔfH?[CaCO3(s)] + ΔfH?[CO2(g)] + ΔfH?[CaO(s)] = 179.1kJ Ca (s) + C (s) + 3/2 O2 (g) ?H1? = 1207.6 kJ CaO (s) + CO2 (g) ?H = ?H1? + ?H2? + ?H3? = 179.1 kJ ?H2? +?H3? = (?635.0) + (?393.