硫化矿氧化自热性质测试的新方法-中国有色金属学报.PDF

20 5 2010 5 Vol.20 No.5 The Chinese Journal of Nonferrous Metals May 2010 1004-0609(2010)05-0976-07 1, 2 1, 2 (1. 410083 2. 410083) 3 3 () 13.736 621.381 736.235 0 kJ/mol3 TD75 A New test method of oxidation and self-heating properties of sulfide ore samples YANG Fu-qiang1, 2, WU Chao1, 2 (1. School of Resources and Safety Engineering, Central South University, Changsha 410083, China; 2. National Research Center of Safety Science and Technology for Metal Mines, Central South University, Changsha 410083, China) Abstract: A new experimental method to test the oxidation and self-heating properties of sulfide ore samples was introduced. This test system is composed of procedure temperature-controlled chest, wire-mesh basket, thermoelectric couples, and auto-recording thermometer. By changing the constant temperature conditions, three sulfide ore samples were tested for the first time by this new method. The self-heating law curves at different temperatures were gained, and the corresponding apparent activation energies of three samples (iron sulfide concentrate, high-sulfur concentrate and original ore) were calculated by crossing-point temperature method, which were 13.736 6, 21.381 7 and 36.235 0 kJ/mol, re