二烷基二硫代磷酸丙烯酸酯作为润滑油添加剂的实验研究.pdfVIP

石油学报(石油加工) 2008年 4月 ACTA PETRClLEI SINICA(PETROLEUM PROCESSING SECTION) 第 24卷第 2期 文章编号：1001—8719(2008)O2—0191—07 二 烷基二硫代磷酸丙烯酸酯作为润滑油 添加剂的实验研究 张龙华 ，李 铭 ，苏 刚 ，刘维民 (1．中国科学院兰州化学物理研究所，甘肃 兰州 730000；2．中国石油兰州润滑油研究开发中心，甘肃 兰州730060 3．中国科学院研究生院，北京 100039) 摘要：实验室合成了3种分子结构不同的二烷基二硫代磷酸丙烯酸酯(ADDP)。通过元素分析、红外和质谱分析确 证了产物的化学组成与结构；采用热重分析仪考察了它们的热稳定性；采用四球摩擦磨损试验机考察了其极压抗 磨性能，并采用扫描电子显微镜分析了试验钢球磨损表面形貌。结果表明，二烷基二硫代磷酸丙烯酸酯的热稳定性 好于商用 ZDDP；ADDP中不同的烷链结构对其抗磨性能的影响不同，带有支链烷基的 ADDP比直链烷基的 ADDP具有更好的极压抗磨作用，可有效改善润滑油产品的极压抗磨性能，具有广阔的工业应用前景。 关 键 词：二烷基硫代磷酸；极压抗磨；摩擦性能 中图分类号：TE624．82 文献标识码：A EXPERIMENTAL STUDY oN ACRYLATE oF DIALKYL DITHIoPHoSPHoRIC ACID AS LUBRICANT ADDITIVES ZHANG Long—hua ， ～，LI Ming ，SU Gang ，LIU Wei—min (1．Lanzhou Institute of Chemical Physics，CAS，Lanzhou 730000，China； 2．Lanzhou Lubricating Oil RD Institute of PetroChina，Lanzhou 730060，China 3．Graduate School of Chinese Academy of Sciences，Beijing 100039，China) Abstract：Three compounds(ADDP)of dialkyl dithiophosphoric acid and acrylate were synthesized in laboratory．The chemical composition and structure of the ADDP and also their thermal stability were analyzed by means of infrared spectroscopy，mass spectroscopy，element analysis and thermo— gravimetric analysis． The extreme pressure and antiwear properties of these ADDP were comparatively investigated on four—ball machines，in which the worn surfaces of the steel ball were analyzed by SEM method．The results indicated that thermal stability of the synthesized ADDP was better than that of commercial ZDDP．The antiwear properties of ADDP with different alkyl structure were different．The ADD