电极过程动力学Chaper 3 Mass transfer概要1.pptVIP

Chapter 3 MASS TRANSPORT AT THE ELECTRODE/ELECTROLYTE INTERFACES Mass transfer Mass transfer : the movement of species in the media (liquid, gas or solid). Rate of mass transfer: the flux of species i, Ji (mol s-1 cm-2) --- the amount of material passing through a unit area within an interval of unit time The modes of mass transfer Diffusion ------ Movement of a charged species driven by a gradient (梯度)of chemical potential (i.e., concentration gradient). The mass transfer in electrochemical systems In an electrochemical cell, various kinds of mass transfer may function, Ji = JiD + JiM + J