气体分子光谱吸收常数的溯源性研究 the traceability of gas molecular .pdf

BIPM Workshop on Global to Urban Scale Carbon Measurements Build Traceability of Spectroscopic Absorption Constant for GHG Wang Defa NIM 30 June -1 July 2015 1 GHG measurements • For space — satellite • For region — Lidar • For point — in situ 2 Traceability of measurement in situ SI KC KC Reference NIMs NIMs materials Equipment calibration and sample test 3 Disadvantage of reference materials • It is difficult to prepare active gas reference materials in cylinder for example CH2O, O3, HNO3 • The stability of low concentration level (ppb or ppt) RM in cylinder is not always satisfied, for example H2S, NH3, HCl • Although dynamic method is a solution, it need a lot of work to keep the dynamic system stable and health • KC at active gas and low concentration is a big challenge, because of hard preparation. 4 Disadvantage of reference materials • It’s not suitable to calibrate the open-path optical equipments by RM directly • There is no gas cell in open-path measurement system —Remote Sensing (RS) —Differential Absorption Lidar (DIAL) • Open-path system is usually based on absolute spectroscopic measurement (ASM) 5 Absolute Spectrosco