油田回注水质的腐蚀性模拟试验研究.docVIP

油田回注水质的腐蚀性模拟试验研究 张强1，冯青青1(，1，1，，1，1 ( 1.上海理工大学环境与建筑学院，上海200093；) EDS能谱分析可得出管线腐蚀的产物对于回注水质恶化的影响作用，最终得出管线的腐蚀是引起回注水质恶化的主要原因。 关键词：回注水质；管线腐蚀；悬浮物；水质分析 Corrosion Simulation Experimental Study of Oilfield Injection Water Quality ZHANG Qiang1，FENG Qingqing1，1，1，1，1 ( 1．School of Environment and Architecture，University of Shanghai for Science and Technology，Shanghai 200093，China；) Abstract: In this paper, aiming at the problem of oilfield reinjection water quality deterioration, this study simulated the field water injection process in pipeline injection process in the lab, the simulative experimental facility was absolutely designed by the ratio of field water injection pipeline .Different material pipeline samples were collected from the experiment, we determine the relevant water-quality indexs and analyzed the elements of suspended solid in water,.and it also analyzed the reasons that reinjection water results in the water injection pipeline corrosion and poor water quality . Results show that pipeline corrosion influenced the oil and total suspended solid contains in reinjection water. Through the EDS?spectrum analyses of suspended solids, the study discussed the functions of pipeline corrosion product to reinjection water quality deterioration. Finally it is concluded that pipeline corrosion is the main cause of reinjection water quality deterioration. Key words: injection water; pipeline corrosion; suspended solids；water quality analysis 近年来，油田注水驱油技术已得到了广泛的应用[]，油田污水作为注水水源回注地层既有利于保护环境，比其他水源好的驱油效果，因而被广泛采用。但是油田污水中含有较高的悬浮固体[]、浮化油[]、细菌[]及有害离子[]等。大量的油田开发实践表明，注水水质是影响注水工艺和效果的主要因素之一[]。对注水水质的研究具有十分重要的现实意义。 油气田腐蚀的研究主要集中在引起腐蚀的气体[]、离子[]、微生物[]，对腐蚀过程及产物的影响[]、模型的建立[]以及对过程的控制上[]。因此研究注水水质的问题尤显重要，水质中含油量和悬浮固体含量的增加会严重堵塞微细注水孔，直接影响注水压力，注水难度增大，含油量和悬浮固体含量也常常作为水质是否恶化的标志[]。从国内外的油田污水回注资料[]来看，各国对水质的具体要求各不一样，油田的注水水质标准各不相同，因而对回注水水质恶化的原因研究较少。 本文针对当前油田回注水水质恶化的问题了研究，所研究的水质主要来源于辽河油田，随着注水的深入，管线中回注水质中的含油量和总悬浮物含量严重超出了B1级标准[21]。为了科学解释水质恶化的原因和现象，利用模拟现场注水流程中管线注水过程，回注水质对15CrMo合金钢的腐蚀作用，验证管线的腐蚀对回注水质中含油量和总悬浮固体含量影