pva控制合成球形碳酸钙 - 南京师范大学学报（工程技术版）.pdf

8 1 () Vo.l 8 No. 1 2008 3 JOURNAL OF NAN JING NORMAL UN IVERSITY ( ENG INEERING AND TECHNOLOGY EDIT ION ) M ar, 2008 PVA 控制合成球形碳酸钙 邹孔标, 王 伟, 卢文庆, 聂素云 ( , , 210097) [ ] ( PVA) , , , , . PVA C aC l , PVA 2 , CaCl , 2 , . [ ] PVA, , CaCO , 3 [ ] Q811. 7 [ ] B [] 1672-1292( 2008) 01-0064-05 Syn t hesis of Spherical CaCO3 by Polyvi nyl A lcohol as A dditive Zou Kongb iao, W ang W e,i LuW enq ing, N ie Suyun ( School of Ch m istry and Environm ntal Sci nc , Nanjing N orm alUn iv rsity, N anjing 210097, Ch ina) A bstrac t: Vat rit typ of CaCO sph rical crystal is b ion ically synth siz d w ith polyvinyl alcohol as organ ic basic sub- 3 stanc , by con trolling th appropriat r action conditions, smi uolating th b iological m in ralization of CaCO . Th 3 ff cts of PVA, CaC l and t m p ratur on th m orphology of CaCO ar inv stigat d. It is found that in th giv n condi- 2 3 tions, CaCO crystal can b succ ssfu lly induc d to grow into a sph rical crystal by adjusting th PVA conc ntration, th 3 siz of vat rit b com s larg r wh n th CaC l conc ntration is d cr as d, surfac structur of vat rit can b chang d 2 wh n t m p ratu