ag+掺杂tio2-ep光催化降解甲基橙废水的研究 - 环境工程学报.doc

拟再审修改稿 银钛共负载型光催化材料降解甲基橙废水的研究 徐荣 葛骁束正华 封克 王小治* （江苏省环境材料与环境工程重点实验室，扬州大学环境科学与工程学院） 摘要 以膨胀珍珠岩为载体，采用溶胶凝胶法对其进行负载，制备出不同类型的光催化材料(TiO2-EP、Ag+-TiO2-EP)，并在模拟日光条件下，研究其对甲基橙溶液的降解效果。结果表明，浸渍3次且担载0.04% Ag+的负载型TiO2光催化活性最高，在光催化剂用量为0.3g，20mL初始浓度为10mg/L甲基橙溶液光照4h后降解率可达81.6%，回收3次后仍有较强的活性，其2h降解率为24.8%。 关键词 膨胀珍珠岩 光催化剂 Ag+-TiO2-EP 甲基橙 Photocatalytic degradation of methyl orange wastewater by Co-deposited（Ag+-TiO2-EP） material Xu Rong Ge XiaoShu Zhenghua Feng Ke Wang Xiaozhi* （Key Laboratory of Environmental Material and Environmental Engineering of Jiangsu Province ; College of Environmental Science and Engineering, Yangzhou University） Abstract Different floating photocatalysts including TiO2-EP and Ag+-TiO2-EP were successfully synthesized by Sol-Gel method using tetrabutyl titanate as precursor and expanded perlite (EP) as support. Under simulative sunlight, the degradation rate of methyl orange by different photocatalysts, as well as the effect of different loading times, the dosage and the initial concentration of methyl orange were investigated. The results showed that Ag+-TiO2-EP which modified three times with Ag+-TiO2 (0.04% Ag+) had the highest photocatalyst ability. The degradation rate of the methyl orange solution (20mL, 10 mg/L) which were decomposed by Ag+-TiO2-EP (0.3g) in 4h was 81.6%. The reaction of photocatalysis for Methyl orange can be expressed as first-order kinetic mode within the concentration range of Methyl orange between 5mg/L and 15 mg/L. Ag+-TiO2-EP still had the relatively higher photocatalytic activity after three times recycling and the degradation rate of methyl orange were 24.8% within 2h. Key words expanded perlite; photocatalysts; Ag+-TiO2-EP; methyl orange (随着工农业的发展，人类向水体中排放的有机污染物日益增多。印染废水具有水量大、有机污染物含量高、色度深、碱性大、水质变化大等特点，其处理难度大[1-2]。TiO2作为一种光催化剂，因具有高活性、安全、廉价、无污染等特点而成为最有前途的绿色环保型催化剂之一，已被应用于印染废水的处理 [3-4]。针对TiO2存在量子效率较低的缺点，常采用掺杂改性的方法，提高光催化效率。其中贵金属Ag+负载至TiO2近来研究较多[5,6]，与其他贵金属掺杂比较，Ag-TiO2的成本低，且其对水体中的细菌和病毒还具有杀灭作用[7,8]，通过TiO2负载于吸附性好、比表面积较大的载体上制成负载型光催化剂，[9,10]