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粘度法测定高聚物的分子量(The viscosity method determines the molecular weight of the polymer)
粘度法测定高聚物的分子量(The viscosity method determines the molecular weight of the polymer)
The viscosity method determines the molecular weight of the polymer
[applicable objects] medicine, pharmaceutical preparation, Chinese medicine, pharmaceutical engineering, Chinese medicine (international communication direction), biological engineering major
[experimental study] 4
I. experimental purpose
1. Grasp the principle of viscosity method to determine the relative molecular weight of high polymer.
2. The viscosity of the polyvinyl alcohol was determined by using the uvil viscosimeter, and the viscosity of polyvinyl alcohol was calculated.
Second, the experimental principle
The polymer can be synthesized by polymerization or condensation polymerization. Not the size of each molecule of a polymer is the same, that is, the polymerization degree is not necessarily the same, so the molar mass of the polymer is a statistical average. For the study of the mechanism and dynamics of polymerization and reconciliation process, and in order to improve and control the performance of high polymer products, the molar quality of polymer is one of the important data that must be mastered.
The high polymer solution is characterized by its high viscosity, because its molecular chain is much larger than solvent molecules, and the solvent is used to make it suffer from internal friction resistance in the flow.
The viscous liquid must overcome the internal friction resistance in the process of flow. The resistances of the resistances are represented by the viscosity coefficient eta (referred to as viscosity), and the viscosity coefficient is expressed (kg · m-1 · s-1).
The viscosity of the dilute solution of high polymer is the reflection of the friction force in the flow of liquid. Pure solvent viscosity reflects the friction between the solvent molecules, as eta 0, the viscosity of the polymer solution is between polymer molecular internal friction, internal friction between polymer molecules and
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