党智敏-嵌入式电容用钛酸钡_聚酰亚胺复合薄膜的制备及性能研究.pdfVIP

14 白晓飞等：嵌入式电容用钛酸钡/聚酰亚胺复合薄膜的制备及性能研究 绝缘材料 2012 ，45(4) 嵌入式电容用钛酸钡/聚酰亚胺复合薄膜的 制备及性能研究 1 2 1 1 2 白晓飞，查俊伟 ，方 也 ，赵 航 ，党智敏 （1.北京化工大学 材料科学与工程学院，北京 100029； 2.北京科技大学 化学与生物工程学院，北京 100083） 摘要：对钛酸钡(BT)纳米粒子进行了表面改性，采用原位聚合法将钛酸钡与聚酰亚胺复合制备了高介电BT/PI 复合薄膜，为了进一步提高介电性能，将第三组分炭黑掺入其中，并对其进行了红外光谱、扫描电镜(SEM)分 析和介电性能测试。结果表明：与未改性的复合薄膜相比，改性后纳米粒子在基体中分散更加均匀，复合薄膜 的介电性能明显提高，可用于制备嵌入式电容中的电介质材料。 关键词: 微观结构；介电性能；复合材料 中图分类号：TM215.3 ；TM206 文献标志码：A 文章编号：1009-9239（2012 ）04-0014-04 Preparation and Properties of BaTiO /PI Composite Film 3 for Embedded Capacitors 1 2 1 1 2 Bai Xiaofei , Zha Junwei , Fang Ye , Zhao Hang , Dang Zhimin (1.College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China; 2. School of Chemistry and Biological Engineering, University of Science Technology Beijing, Beijing 100083, China) Abstract: A barium titanate(BaTiO )/polyimide(PI) composite film with high dielectric properties was pre- 3 pared from modified BaTiO3 (BT) and PI by in-situ polymerization. In order to enhance the dielectric properties, a three-phase composite with adding carbon black was prepared. The composite was analyzed by FTIR, SEM and the dielectric properties were studied. The results show that compared with unmodi- fied BT particle, the modified nanopa