（co-condensation NMR )preparation of ordered large pore SBA-15 silica functionalized with aminopropyl groups through one-pot synthesis.pdfVIP

Preparation of ordered large pore SBA-15 silica functionalized with aminopropyl groups through one-pot synthesis{ Xueguang Wang, Kyle S. K. Lin, Jerry C. C. Chan and Soofin Cheng* Department of Chemistry, National Taiwan University, Taipei 106, Taiwan. E-mail: chem1031@.tw; Fax: 1886-2 Received (in Cambridge, UK) 28th May 2004, Accepted 1st September 2004 First published as an Advance Article on the web 8th October 2004 Highly ordered large pore SBA-15 silica functionalized with TEOS pre-hydrolysis show one very intense peak and two weak up to 16% aminopropyl groups, which gave high catalytic peaks indexed to (100), (110), and (200) or (210) reflections, activity and selectivity toward flavanone synthesis through respectively, indicating that significant improvement of long range aldol condensation and subsequent intramolecular Michael ordering of the hexagonal arrayed pore structure could be achieved addition of benzaldehyde and 2’-hydroxyacetophenone, was by pre-hydrolysis of TEOS before the introduction of APTES. The synthesized for the first time via co-condensation of peak intensity of the samples weakens as the amino loading tetraethylorthosilicate (TEOS) and 3-aminopropyltrieth- increases, implying that the aminopropyl groups still have some oxysilane (APTES) using an amphiphilic block copolymer as interference on the assembly of the mesophase. Nevertheless, the the structure-directing agent. TEM micrograph