超声波_微波法制备NiW_Al_2O_3加氢脱硫催化剂_刘学芬.pdf

25 9 　　　 2004 9 Vol.25 No.9 Chinese Journal of Catal sis September 2004 :0253-9837(2004)09-0748-05 :748～752 -NiW/Al O 2 3 刘学芬, 　张　乐, 　石亚华, 　聂　红, 　龙湘云 (中国石油化工股份有限公司石油化工科学研究院, 北京 100083) : NiW/Al O (H S), , 2 3 ., .X ., NiW/Al O 2 3 , , ., , . , . :, , , , , , , :O643　　　:A Preparation of NiW/Al O Hydrodesulfurization Catalyst 2 3 by Ultrasound-MicrowaveTreat ent ＊ LIU Xuefen , ZHANG L e, SHI Yahua, NIE Hong, LONG Xiangyun (Research Institute of Petroleum Processing, S INOPE C, Beij ing 100083, China) Abstract:Hydrotreating is one of the important means for the production of clean fuels and its efficiency largely depends on the hydrotreating catalysts.Thepreparation methods greatly influence thenatureof the catalysts and result in different activity, selectivity and stability.In the present study, the NiW/Al O catalyst was prepared 2 3 by impregnation combined with ultrasound treatment and microwave drying.The catalytic properties, surface state and morphology of the catalyst were examined by using thiophene hydrodesulfurization, XPS and TEM techniques, respectively .The as-prepared catalyst exhibited higher hydrodesulfurization activity than that ob- tained by the conventional method.The XPS and TEM analysis revealed that combination of the ultrasound treatment and microwave drying could promote the sulfuration and surface dispersion of the active metals and produce moreunsaturated“rim”and “edge”sites in the WS2 slabs.As a result,