Au催化剂在液相选择性加氢反应中的应用进展_邢铁锋.pdfVIP

2009 38 3 PETROCHEM ICA L TECHNOLOGY # 329# Au 邢铁锋, 刘迎新, 寻增才, 严 巍 ( , 310032) [] AuA, B- /, A u Au , Au , A uAuA u [] ; ; ; A, B- ; A, B- ; [] 1000- 8144 ( 2009) 03- 0329- 06 [ ] TQ 426 [] A Advan ce in L iquid-Pha se Selective Hydrogenation ov er Gold C atalyst X in Tiefen , Liu Yin xin, Xun Zen ca i, Yan W ei ( Research and D evelopm ent Base of C ataly ticH ydro en ation of Z hejian U n iversity o f T echno lo y, State Key Labo rato ry Breedin B ase of G reen Chem istry SynthesisT echno lo y, H an zhou Z hejian 310032, Ch ina) [ A bstract] The old cataly sts by load in o ld nanoparticles on different ox ide supports, nam ely T iO , Z rO , CeO and Fe O , exh ib ited h i h catalytic activity and selectivity in som e ox idation 2 2 2 2 3 reduction reactions. A pplication of the above o ld cataly sts in liquid-phase selective hydro enation of som e un saturated compounds includ in un saturated hydrocarbon, A, B-unsaturated aldehydes/ketones and nitro roup com pounds w as summ arized. The m echan ism s of hydro en adsorption and hydro enation of different unsaturated compounds on o ld cataly sts w ere discussed. Some opinions about the research of old cataly sts, includin their preparation, catalyticm echan ism and m easures for enhancem ent of their stability w ere iven. [ K eywords] old cataly st; liqu id-phase selective hydro enation; unsaturated hydrocarbon; A, B- unsaturated aldehyde; A, B-unsaturated ketone; n itro roup compound , A u Au [ 1] 1989 Haruta , 10 , nm A u, CO A u A u,