污泥热水解过程中有机物分子量和荧光特征变化规律 - 污泥碳化.pdf

中国环境科学 2008,28(12) ：1062~1067 China Environmental Science 污泥热水解过程中有机物分子量和荧光特征变化规律 1,2 1* 欧阳二明 ,王 伟 (1.清华大学环境科学与工程系,北京 100084 ；2.南昌大学建筑工程学院,江西 南昌 330031) 摘要：运用三维荧光光谱技术对污泥热水解过程中不同分子量范围内有机物的荧光特性进行了研究.结果表明,在原污泥和热水解污泥各 分子量范围内均有 4 个明显的荧光峰:Peak A [E /E 为(240~260nm)/(379~457nm)]、Peak B [E /E 为(275~290nm)/(305~351nm)]、Peak C x m x m [E /E 为(315~340nm)/(372~445nm)]和 Peak D [E /E 为(350~425nm)/(438~495nm)],分别为紫外区类富里酸荧光、类蛋白荧光、可见区类 x m x m 富里酸荧光、类腐殖酸荧光.污泥中的类富里酸荧光物质和类腐殖酸荧光物质在热水解过程中发生的主要反应是溶解液化,而类蛋白荧光 物质发生的主要反应是水解反应. 关键词：污泥；热水解；分子量分布；三维荧光光谱 中图分类号：X131.2 文献标识码：A 文章编号：1000-6923(2008)12-1062-06 The change of spectroscopic characterization and molecular weight distribution in sludge thermal hydrolysis process. OUYANG Er-ming1,2, WANG Wei1*, (1.Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China ；2.School of Civil Engineering and Architecture, Nanchang University, Nanchang 330031, China). China Environmental Science, 2008,28(12)：1062~1067 Abstract ：Three-dimensional excitation emission matrix fluorescence spectroscopy (3DEEM) was applied to characterize the change of different molecular weight organic matter in sludge thermal hydrolysis process. Four fluorescence peaks were identified in 3DEEM of the raw sewage sludge and thermal-hydrolyzed sewage sludge: Peak A, Peak B, Peak C and Peak D, which could be attributed to the UV fulvic-like fluorophore, the protein-like fluorophore, the visible fulvic-like fluorophore and the humic-like fluorophore respectively. Results of the peak intensity in different molecular weight organic matter in raw sewage sludge and thermal-hydrolyzed sewage sludge showed that: