交联壳聚糖吸附处理低浓度含铀废水.pdf

SeriesNo. 411 金 属 矿 山 总第411期 September 2010 METAL M INE 2010年第 9期 交联壳聚糖吸附处理低浓度含铀废水* 王学刚 王光辉 谢志英 (东华理工大学 ) (CTS), , (CCTS), , pH , pH= 3~ 5, 10 mg, 50mg/ L, 160 m in, 98. 0% , Langmuir, 50mg/L, 87. 4%, 98. 0%, 交联壳聚糖 吸附 含铀废水 Adsorption ofUranium in Low ConcentrationUraniumbearing Wastewater onto Crosslinked Chitosan WangXuegang W ang Guanghui Xie Zhiying (E ast Ch ina Institu te of T echnology ) Abstract Taking the natural polymer compounds of chitosan as rawmaterials, the insoluble crosslinked chitosanwas synthesized by the reaction of chitosan w ith epichlorohydrin under alkaline conditions as the adsorbent of uraniumbearing wastewater. The influence factors on adsorption of uranium were investigated in details, such as pH value, adsorbent dos age, uranium initial concentration, particle size and equilibrium of adsorption and the adsorption kinetics law ofuranium on crosslinked chitosan were described. The results show thatunder the conditions ofpH= 3~ 5, adding 10mg crosslinked chitosan, the adsorption equilibrium for the 50 mg/L uranium can be obtained after 160m in of adsorption, and the adsorp tion removal efficiency of crosslinked chitosan for uranium was over 98. 0%. The adsorption law ofuranium on crosslinked chitosan followed the Langmuir model very well and the pseudo secondorder kineticsmodelwas used to describe the ad sorption process. W hen the initial concentrations of uranium is50mg/L, the adsorption removalefficiency of chitosan and crosslinked chitosan for uranium is87. 4% and98. 0% respectively, and the absorbability of crosslinked chitosanwas mi proved significantly. Keywords Cro