微合金碳氮化物的结构与析出形态张根元.pdf

24 5 Vol. 24 No. 5 2000 10 M aterialsforM echanical Engineering Oct . 2000 * ( 河海大学机电工程学院　江苏常州213022) ( 铁道部戚墅堰机车车辆工艺研究所　江苏常州213011) 研究了含钒、钛 素的Fe-C 合金中碳氮化物的析出相形貌、结构和化学组成的关 系, 指出了方形和球形析出相结构为( T ix V 1- x ) C( N) , 等温温度较高时形成碳氮化钒中富集较多 钛, 而等温温度较低时形成碳氮化钒中含有极微量或不含钛, 片状相结构为V C( N) 。碳氮化物析出 相有弥散析出、相间析出、纤维状析出及等温转变温度较低时, 碳氮化物在铁素体晶内沿位错处弥 散析出等形态。本工作出现的纤维状析出可能是细小片状碳氮化物粒子溶合而成。 碳氮化物　析出形态　结构 Structure and Precipitation Morphology of Microalloy Carbonitride Zhang Genyuan( Hehai UniversityChangzhou iang su 2 13022) Jiang Ke ( Qishuyan Iocomotive and Rolling Stock T echnology Research Institute Changzhou iang su 213011) Abstract T he relatio nships of V , T i carbonit rides morpholo gy , structure , chemical co mpo sition ar e studied, it is investig ated that cubic or spheric pr ecipitat ion is V C ( N ) co ntained T i at higher isothermal temperat ur e and contained litter or never T i at lower isother mal temper ature, a plat precipit atio n is V C( N) . It has been found that interphase pr ecipitatio n, fibrous pr ecipitation, precipitatio n on dislocation, precipitatio n fro m super sat ur ated ferrite at low er isot her mal t ransfor med t em per ature . Fibr ous pr ecipitation in t his paper gr owths by dissolv ing of litter plate V C( N) phase. 30m in 1 : 1150 C 30min , [ 1] , 580 C630 C680 C730 C780 C 50% BaCl2 + 25%NaCl+ 25%KCl [ 2, 3] ( - - )