金属氧化物对CO 还原NO 反应的催化作用 - 环境科学.PDF

1999 1 ENVIRONM ENTA L SCIENCE Jan. , 1999 * CO NO 徐春保　吴胜利　苍大强　寿秋爽　李　敏　邓　勇 ( , 100083) , CuOCr O Mn O F O Ni O CO 2 3 2 2 3 2 3 3 NO . , 500 800ml/m NO-0. 2% CO-2. 0% CO -N CO NO , 2 2 ( SRR) 1. 50% . CO NO , F O Ni O 2 3 2 3 F -Ni-O N i-Cu-O Ni-Cu -M n-O , S RR 100. 00% , 96. 10% , 100. 00% , x x x 100. 00% 100. 00% . CO NO R dox . , , , CO NO , . The Catalytic Performance of Several Metallic Oxides and Complex Metallic Oxides on Reaction of CO Reducing NO Xu ChunbaoWu Sh ngliCang Daqiang Shou Qiushuang Li M inD ng Yong ( M tallurgical Engin ring School, U niv. of Sci nc T chnology B ijing, B ijing 100083) AbstractT h catalytic activiti s of CuO, Cr2 O3, M nO2 , F 2O3 and Ni2O3 and th compl x , m tallic oxid s form d by th singl oxid s on r duction of NO by CO w r studi d in a 3 pack d-b d r actor. Th r sults show d that in th atmosph r of 800ml/ m NO-0. 2% CO- 2. 0% CO2 -N2 w ith th pr h ating t mp ratur of 500 it w as difficult to r duc NO by CO, w ith th stabl r duction ratio ( SRR) of NO only 1. 5%. All m tallic ox id s and compl x m tallic oxid s us d in th pr s nt xp rim nts gav c rtain catalytic ff ct on r duction of NO by CO. F 2O3, Ni2O3, F -Ni-Ox , Ni-Cu-Ox and Ni-Cu-Mn-Ox show d high ctalytic activiti s on , 100. 00%, 96. 10%, 100. 00%, 100. 00% 100. 00% r duction of NO by CO