Application of heterogeneous colloid catalysts for the preparation of fine chemicals：（异构的应用胶体催化剂制备精细化学品）.pdfVIP

Topics in Catalysis 4 (1997) 217–227 217 Application of heterogeneous colloid catalysts for the preparation of fine chemicals H. Bonnemann , W. Brijoux, A. Schulze Tilling and K. Siepen ¨ Max-Planck-Institut fur Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45466 Mulheim an der Ruhr, Germany ¨ ¨ Preprepared nanometals stabilized by surfactants may be used as precursors for a new type of heterogeneous catalyst. Independent of the support these mono- or plurimetallic precursors may be optimized dependent on the size, composition, and structure of the particles. Further, the active metal surface may be shielded against poisons by the protective shell. In addition, doping agents may be used in order to enhance the catalytic performance. The cis-selective partial hydrogenation of 3-hexyn-1-ol giving leaf alcohol, a valuable fragrance, and the selective oxidation of glucose giving sodium gluconate are current examples for the application of supported nanometal colloids in fine chemicals catalysis. Keywords: metal-colloid catalysts, selective cis-hydrogenation, leaf alcohol, glucose-oxidation 1. A Pb-promoted Pd-colloid catalyst on CaCO3 for virtually no effect, the type of the surfactant (cationic vs. the cis-selective hydrogenation of 3-hexyn-1-ol [1] zwitterionic), the chain length of the lipophilic alkyl groups in the stabilizer, and the support were found to have a sig- 1.1. I