浅谈白酒中杂醇油的分析方法.docVIP

浅谈白酒中杂醇油的分析方法 王珍, 周洋, 李春丽,徐志勇1，许引虎，曲树蓬— 威龙葡萄酒股份有限公司，山东 烟台 265701； 2. 安琪酵母股份有限公司，湖北 宜昌 443000 3. 烟台联创海悦检测有限公司，山东 烟台 265701） 摘要 在白酒的酿造过程中,不可避免的会产生杂醇油。杂醇油包括正、异丙醇,正、异丁醇，正、仲戊醇等等。杂醇油具有一定的毒性，含量过高时会使人产生头痛，头晕等。要控制白酒中杂醇油的含量，目前国标中规定的测杂醇油的方法主要是气相色谱法跟分光光度法。为提高分析的准确性，对分光光度法的实验条件进行了优化。另外，对气相色谱法也有进一步的发展优化，比如采用内标物，程序升温法，毛细管柱法，顶空固相微萃取与气相色谱法连用，等等。 The analysis methods of the fusel oil in alcoholic liquor WEILONG GRAPE WINE CO., LTD ANGEL YEAST CO., LTD Yantai Lianchuang Haiyue Detection Co.,Ltd WANG zhen,ZHOU yang,LI chunli, Xu yinhu and QU shunpeng Abstract In the process of brewing alcoholic liquor,it will inevitably produce fusel oil . Fusel oil includs n-propanol, isopropanol, n-butanol, isobutanol, isoamyl alcohol, sec-amyl alcohol, etc..Fusel oil is poisonous. If The content of fusel oil is too high,people will have a headache and dizziness. To control the content of fusel oil of alcoholic liquor,the authorized national standard analytical methods to fusel oil are gas chromatography and spectrophotometric method. In order to improve the accuracy of the analysis, the experimental condition is optimized for spectrophotometric method. In addition, the development of gas chromatography is improving, such as the internal standard, process icrease temperature, capillary column gas chromatography, headspace solid-phase microextraction and gas chromatography, and so on. 关键字：杂醇油； 气相色谱法； 分光光度法 Keywords:fusel oil； gas chromatography； spectrophotometric method 参考文献： ［］［］［］［］［］